Dioxygen Affinity and Catalytic Performance of Bis-(furaldehyde) Schiff Bases Co(II) Complexes in Cyclohexene Oxidation

被引：0
|
作者：
Bin SUN
机构：
来源：
Chinese Chemical Letters | 2001年 / 11期
关键词：
Schiff base; cobalt (II) complex; oxygenation; catalytic oxidation; cyclohexene;
D O I：
暂无
中图分类号：
O626 [杂环化合物];
学科分类号：
摘要：
Oxygenation constants and thermodynamic parameters DHo and DSo of cobalt (II) complexes with bis-(furaldehyde) Schiff bases (1, 2, 3, 4)were obtained by mearsuring saturated dioxygen uptake of these complexes in pyridine at different temperature. These complexes could activate molecular oxygen and were used as catalysts in cyclohexene oxidation. The influence of ligand structure on the dioxygen affinity and catalytic activity of the complexes were discussed.
引用
收藏
页码：1043 / 1046
页数：4
相关论文
共 50 条
  • [31] Dioxygen affinities and catalytic oxidation performance of cobalt (II)complexes with N-aryl hydroxamic acid
    Zhang, CC
    Zeng, W
    Li, JZ
    Qin, SY
    CHINESE CHEMICAL LETTERS, 2003, 14 (06) : 627 - 630
  • [32] THE CATALYTIC ACTIVITY OF A TRICYCLIC CU(II) COMPLEX WITH TETRAHEDRAL BIS(OXA,AZA)-CHELATE CORE IN LIQUID-PHASE CYCLOHEXENE OXIDATION BY DIOXYGEN
    ZAKHAROV, AN
    NEZLOBINA, EI
    PANOVA, GV
    KINETICS AND CATALYSIS, 1993, 34 (06) : 917 - 921
  • [33] Synthesis, oxygenation and catalytic activity of crowned bis-Schiff bases cobalt complexes
    Sun, B
    Chen, JR
    Hu, JY
    Li, XJ
    ACTA CHIMICA SINICA, 2001, 59 (09) : 1418 - 1423
  • [34] Polymeric complex of Mn(II), Co(II), Ni(II), Cu(II) and Zn(II) with schiff bases derived from hydroquinone bis-(acetylhydrazide) and aromatic aldehydes
    Vivekanand
    Bhandari, N. S.
    ASIAN JOURNAL OF CHEMISTRY, 2007, 19 (06) : 4225 - 4230
  • [35] Ruthenium(II) carbonyl complexes containing tetradentate Schiff bases and their catalytic activities
    Viswanathamurthi, P
    Natarajan, K
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2006, 36 (05) : 415 - 418
  • [36] PARAMAGNETIC-RESONANCE OF CO(II) COMPLEXES WITH SCHIFF-BASES
    YABLOKOV, YV
    SHISHKOV, VF
    VORONKOV.VK
    KOGAN, VA
    OSIPOV, OA
    ZHURNAL NEORGANICHESKOI KHIMII, 1972, 17 (02): : 410 - &
  • [37] SYNTHESIS AND CHARACTERIZATION OF Co(II) COMPLEXES WITH TRIDENTATE (ONO) SCHIFF BASES
    Dehari, Dije
    Podvorica, Fetah
    Dehari, Shefket
    Shehabi, Muhamet
    STUDIA UNIVERSITATIS BABES-BOLYAI CHEMIA, 2012, 57 (04): : 33 - 38
  • [38] Investigation of catalytic activity of new Co(II) phthalocyanine complexes in cyclohexene oxidation using different type of oxidants
    Kamiloglu, Ayse Aktas
    Saka, Ece Tugba
    Biyiklioglu, Zekeriya
    Acar, Irfan
    Kantekin, Halit
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2013, 745 : 18 - 24
  • [39] Synthesis & characterization of zinc(II), cadmium(II) & mercury(II) complexes with bis(bidentate) Schiff bases
    Das, MK
    Ghosh, S
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1998, 37 (03): : 272 - 275
  • [40] Cis-Dioxo-molybdenum(VI) Complexes with Diaminoguanidinium and Triaminoguanidinium Schiff Bases and Their Catalytic Application for Epoxidation of Cyclohexene
    Jia, Ai Q.
    Zhou, Wen Y.
    Wu, Si M.
    Shi, Hua T.
    Zhang, Qian F.
    CHEMISTRYSELECT, 2020, 5 (36): : 11085 - 11095
12345