Dioxygen Affinity and Catalytic Performance of Bis-(furaldehyde) Schiff Bases Co(II) Complexes in Cyclohexene Oxidation

被引：0
|
作者：
Bin SUN
机构：
来源：
Chinese Chemical Letters | 2001年 / 11期
关键词：
Schiff base; cobalt (II) complex; oxygenation; catalytic oxidation; cyclohexene;
D O I：
暂无
中图分类号：
O626 [杂环化合物];
学科分类号：
摘要：
Oxygenation constants and thermodynamic parameters DHo and DSo of cobalt (II) complexes with bis-(furaldehyde) Schiff bases (1, 2, 3, 4)were obtained by mearsuring saturated dioxygen uptake of these complexes in pyridine at different temperature. These complexes could activate molecular oxygen and were used as catalysts in cyclohexene oxidation. The influence of ligand structure on the dioxygen affinity and catalytic activity of the complexes were discussed.
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页码：1043 / 1046
页数：4
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