Hydrothermal Synthesis, Crystal Structure and Luminescence Property of a 2D Manganese(Ⅱ) Coordination Polymer

被引：3
|
作者：
郁有祝 [1 ]
常颂扬 [1 ]
韩曦 [1 ]
陈广鑫 [1 ]
轩亚威 [1 ]
武现丽 [2 ]
王芳 [1 ]
机构：
[1] College of Chemistry and Environmental Engineering,Anyang Institute of Technology
[2] College of Chemistry and Molecular Engineering,Zhengzhou University
来源：
Chinese Journal of Structural Chemistry | 2019年 / 38卷 / 01期
基金：
中国国家自然科学基金;
关键词：
synthesis; crystal structure; Mn(Ⅱ) complex; photoluminescent property;
D O I：
10.14102/j.cnki.0254-5861.2011-2035
中图分类号：
O641.4 [络合物化学（配位化学）];
学科分类号：
070304 ; 081704 ;
摘要：
Solvothermal reactions of MnCl;·4H;O with（pyridin-2-yl）methyl 4-(2-(4-(（pyridin-2-yl）methoxy)phenyl)diazenyl)benzoate（L1） via an in situ ligand transformation reaction produced a new coordination polymer, {[Mn;Cl;L;（H;O）]·H;O};(1, where HL = 4-(2-(4-(（pyridin-2-yl）methoxy)phenyl)diazenyl)benzoic acid). The L1 ligand was decomposed in situ to L;which was coordinated with Mn（Ⅱ） to form compound 1 in the solvothermal synthesis process. Complex 1 was characterized by IR spectroscopy, powder X-ray diffraction and single-crystal X-ray diffraction.Compound 1 possesses a 2D network. In addition, stability and photoluminescent property of 1 were also investigated.
引用
收藏
页码：147 / 154
页数：8
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