Hydrothermal Synthesis, Crystal Structure and Luminescence Property of a 2D Manganese(Ⅱ) Coordination Polymer

被引：3

作者：

郁有祝 ^{[1
]}

常颂扬 ^{[1
]}

韩曦 ^{[1
]}

陈广鑫 ^{[1
]}

轩亚威 ^{[1
]}

武现丽 ^{[2
]}

王芳 ^{[1
]}

机构：

[1] College of Chemistry and Environmental Engineering,Anyang Institute of Technology

[2] College of Chemistry and Molecular Engineering,Zhengzhou University

来源：

Chinese Journal of Structural Chemistry | 2019年 / 38卷 / 01期

基金：

中国国家自然科学基金;

关键词：

synthesis; crystal structure; Mn(Ⅱ) complex; photoluminescent property;

D O I：

10.14102/j.cnki.0254-5861.2011-2035

中图分类号：

O641.4 [络合物化学（配位化学）];

学科分类号：

070304 ; 081704 ;

摘要：

Solvothermal reactions of MnCl;·4H;O with（pyridin-2-yl）methyl 4-(2-(4-(（pyridin-2-yl）methoxy)phenyl)diazenyl)benzoate（L1） via an in situ ligand transformation reaction produced a new coordination polymer, {[Mn;Cl;L;（H;O）]·H;O};(1, where HL = 4-(2-(4-(（pyridin-2-yl）methoxy)phenyl)diazenyl)benzoic acid). The L1 ligand was decomposed in situ to L;which was coordinated with Mn（Ⅱ） to form compound 1 in the solvothermal synthesis process. Complex 1 was characterized by IR spectroscopy, powder X-ray diffraction and single-crystal X-ray diffraction.Compound 1 possesses a 2D network. In addition, stability and photoluminescent property of 1 were also investigated.

引用

页码：147 / 154

页数：8

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