Syntheses, Structures and Photoluminescence of Two New Europium(Ⅲ) Coordination Polymers

被引：0
|
作者：
李敏 [1 ]
黄群增 [2 ]
冯玉全 [2 ]
石恒真 [2 ]
机构：
[1] Department of Chemistry, Henan Institute of Education
[2] College of Chemistry and Pharmacy Engineering, Nanyang Normal University
来源：
Chinese Journal of Structural Chemistry | 2012年 / 31卷 / 08期
关键词：
coordination polymer; lanthanide; photoluminescence;
D O I：
10.14102/j.cnki.0254-5861.2012.08.004
中图分类号：
O631.3 [高聚物的化学性质];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Two new europium (Ⅲ) coordination polymers formulated as Eu2(H2O)2(ox)4 ]· (C5H6N)2 ·2H 2 O(1) and Eu 2(ad)3(H2O)4 ]·0.25H2O (2) (H2ox = oxalic acid, H2ad = adipic acid) have been synthesized from the self-assembly of lanthanide ions Eu 3+ with flexible oxalic and adipic acid ligands, respectively. Structural analyses revealed that complex 1 exhibits three-dimensional metalorganic frameworks, and 2 has intricate two-dimensional interpenetrated metal-organic networks. In addition, the photoluminescent properties of complexes 1 and 2 were discussed in detail, which shows strong red emission, corresponding to 5 D0 → 7 F 2 transition of Eu3+ ions.
引用
收藏
页码：1067 / 1074
页数：8
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