TWO NEW 1D COORDINATION POLYMERS: SYNTHESES, STRUCTURES AND PROPERTIES

被引：2

作者：

Wu, Jian ^{[1
]}

Wang, Fu-Min ^{[2
]}

Liu, Jian-Qiang ^{[3
]}

Chen, Jia-Xi ^{[3
]}

Wu, Jia-Min ^{[3
]}

Li, Kai-Bang ^{[1
]}

Wei, Yi ^{[1
]}

Li, Qing-Lin ^{[3
]}

机构：

[1] Guangxi Univ Nationalities, Coll Chem & Chem Engn, Guangxi Key Lab Chem & Engn Forest Prod, Nanning 530006, Guangxi, Peoples R China

[2] Shaanxi Xueqian Normal Univ, Dept Chem & Chem Engn, Xian 710100, Shannxi, Peoples R China

[3] Guangdong Med Coll, Sch Pharm, Dongguan 523808, Peoples R China

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF ETHIOPIA | 2014年 / 28卷 / 03期

关键词：

Structure; Supramolecular interaction; Luminescence; METAL-ORGANIC FRAMEWORKS; CRYSTAL; LIGANDS; DESIGN;

D O I：

10.4314/bcse.v28i3.11

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two new coordination polymers, namely, [Zn(bi)(Cl)(2)](n) (1) and [Cu(L)(2)(bib)(H2O)(2)](n) (2) (bi = 4,4'-bis(2-methylimidazol-1-ylmethyl)biphenyl; L = 4-(2-(4-(methoxycarbonyl)phenoxy) ethoxy) benzoic acid and bib = 2,3-bis(4-pyridyl)butane), are synthesized and characterized. Both of 1 and 2 have 1D covalent chains, which show different conformally chain feature. 2D supremolecular rhombic and rectangle motifs are observed in 1 and 2, respectively. The O-H center dot center dot center dot O and C-H center dot center dot center dot Cl hydrogen-bonding interactions play a significant role in promoting the diversity of structural patterns.

引用

页码：415 / 422

页数：8

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