Synthesis,Structure and Biological Activity of Zn(II) Complex with Tris(benzimidazol-2-yl-methyl)amine Ligand

被引：0
|
作者：
刘小兰
赵茹
刘晓红
岳俊杰
尹宇新
孙云
孙命
机构：
[1] College of Chemistry and Life Science
[2] Tianjin Normal University
[3] Tianjin Normal University Tianjin 300074
[4] China
[5] China The Department of Ministry Logistics Port
[6] Naval Logistics Institute
[7] Tanggu
[8] Tianjin 300400
[9] China Key Laboratory of Bioorganic Phosphorous Chemistry
[10] Department of Chemistry
[11] Tsinghua University
[12] Beijing 100084
来源：
ChineseJournalofChemistry | 2004年 / 01期
关键词：
Zn(II) complex; tris(benzimidazol-2-yl-methyl)amine; superoxide dismutase (SOD); SOD model compound;
D O I：
暂无
中图分类号：
O627 [元素有机化合物];
学科分类号：
070303 ; 081704 ;
摘要：
A new Zn(II) mononuclear complex with tris(benzimidazol-2-yl-methyl)amine (NTB) was synthesized with stoichiometry of [Zn(NTB)NO3]NO3·DIPY·DMF (DIPY∶4,4’-dipyridyl). The complex was characterized by elemental analysis, UV and IR spectra. The crystal structure was determined by using X-ray diffraction analysis. The crystal structure indicates that four N atoms and one O atom coordinate to zinc ion to construct a distorted trigonal-dipyramid configuration. Three nonprotonated N atoms from imidazole groups are in the equatorial plane, one alkylamino N atom and one O atom from 3NO- in the axial directions. The biological activity assay shows that this complex presents certain biological activity by means of pyrogallol autoxidation and it can be called a model compound of superoxide dismutase (SOD).
引用
收藏
页码：75 / 79 +3
页数：6
相关论文
共 50 条
  • [21] Molecular structure of tris[(6-bromopyridin-2-yl)-methyl]amine
    Yan, Ran
    Dai, Zhaohua
    Shlian, Daniel G.
    Mitchell, Trinit'y D.
    Loo, Aaron
    Mulosmani, Kaltrina
    Upmacis, Rita K.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2024, 80 : 1006 - +
  • [22] Theoretical and experimental studies of phenol oxidation by ruthenium complex with N,N,N-tris(benzimidazol-2yl-methyl)amine
    J. Guadalupe Hernandez
    Antonio Romero Silva
    Pandiyan Thangarasu
    Rafael Herrera Najera
    Alfonso Duran Moreno
    M. Teresa Orta Ledesma
    Julian Cruz-Borbolla
    Narinder Singh
    Journal of Molecular Modeling, 2015, 21
  • [23] Theoretical and experimental studies of phenol oxidation by ruthenium complex with N,N,N-tris( benzimidazol-2yl-methyl) amine
    Guadalupe Hernandez, J.
    Romero Silva, Antonio
    Thangarasu, Pandiyan
    Herrera Najera, Rafael
    Duran Moreno, Alfonso
    Orta Ledesma, M. Teresa
    Cruz-Borbolla, Julian
    Singh, Narinder
    JOURNAL OF MOLECULAR MODELING, 2015, 21 (09)
  • [24] Synthesis, characterization and antimicrobial activity of Fe(II), Zn(II), Cd(II) and Hg(II) complexes with 2,6-bis(benzimidazol-2-yl) pyridine ligand
    Aghatabay, Naz M.
    Neshat, A.
    Karabiyik, T.
    Somer, M.
    Haciu, D.
    Dulger, B.
    EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY, 2007, 42 (02) : 205 - 213
  • [25] Synthesis, structure, and antioxidative properties of a copper(II) complex with 1,2-bis(benzimidazol-2-yl)ethane ligand
    Tang Xia
    Qu Yao
    Wang Cong
    Wu Yancong
    Zhao Kun
    Wu Huilu
    JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 2020, 67 (04) : 585 - 591
  • [26] Synthesis, Structure and Spectral, and Electrochemical Properties of New Mononuclear Ruthenium(III) Complexes of Tris[(benzimidazol-2-yl)methyl]amine: Role of Steric Hindrance in Tuning the Catalytic Oxidation Activity
    Murali, Mariappan
    Mayilmurugan, Ramasamy
    Palaniandavar, Mallayan
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2009, (22) : 3238 - 3249
  • [27] Synthesis, structure and fluorescence analysis of three Zn(II) complexes based on (1-methyl-1H-benzimidazol-2-yl) methanol
    Li Shi-Xiong
    Chen Yu-Huan
    Yang Shao-Long
    Yan Mu-Lun
    Wei Cheng-Ting
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2023, 39 (09) : 1782 - 1790
  • [28] Bis{tris[(1H-benzimidazol-3-ium-2-yl)methyl]amine} tetraaquaocta-μ2-chlorido-octachloridopentacadmate(II) monohydrate
    Yu, Chun-Hua
    Zhu, Run-Qiang
    Jin, Yu
    Liu, Ming-Liang
    Jin, Lei
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2013, 69 : 811 - +
  • [29] Studies on zinc(II) iodide complex with tripod ligand tris(2-(N-methyl)benzimidazylmethyl)amine
    Wu, Huilu
    Lv, Weibin
    Qi, Biao
    Liu, Jigang
    Liu, Peng
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2008, 38 (04) : 347 - 351
  • [30] Synthesis, Structure and Photoluminescent Properties of Zn(II)/Cd(II)-Complexes Containing 2,4,6-Tris-(benzimidazolyl-2-yl)pyridine Ligand
    Li Cuijin
    Guo Qingbing
    Yin Guoqiang
    Jiang Xuhong
    Gong Sheng
    CHINESE JOURNAL OF CHEMISTRY, 2011, 29 (07) : 1395 - 1400
12345