Improved two-step hydrothermal process for acetic acid production from carbohydrate biomass

被引：0
|
作者：
Zhibao Huo [1 ]
Yan Fang [2 ]
Guodong Yao [1 ]
Xu Zeng [1 ]
Dezhang Ren [1 ]
Fangming Jin [1 ]
机构：
[1] School of Environmental Science and Engineering, the State Key Laboratory of Metal Matrix Composites,Shanghai Jiao Tong University
[2] State Key Laboratory of Pollution Control and Resources Reuse, College of Environmental Science and Engineering,Tongji University
来源：
Journal of Energy Chemistry | 2015年 / 02期
基金：
中国国家自然科学基金; 国家自然科学基金重点项目;
关键词：
carbohydrate biomass; lactic acid; CuO; acetic acid; hydrothermal reactions;
D O I：
暂无
中图分类号：
TQ225.122 [];
学科分类号：
0817 ;
摘要：
An improved two-step process for converting carbohydrate biomass to acetic acid under hydrothermal conditions is proposed. The first step consists of the production of lactic acid from carbohydrate biomass, and the second step consists of conversion of the lactic acid obtained in the first step to acetic acid using CuO as an oxidant. The results indicated that CuO as an oxidant in the second step can significantly improve the production of high-purity acetic acid from lactic acid, and the maximum yield of acetic acid was 61%, with a purity of 90%. The yield of acetic acid obtained using the improved two-step hydrothermal process from carbohydrate biomass, such as glucose, cellulose and starch, was greater than that obtained using traditional two-step process with H2O2 orO2. In addition, a proposed pathway for the production of acetic acid from lactic acid in the second step with CuO was also discussed. The present study provides a useful two-step process for the production of acetic acid from carbohydrate biomass.
引用
收藏
页码：207 / 212
页数：6
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