An Extended Cu(Ⅱ) Complex Structure Sustained by Hydrogen Bonding and C-H…π Interactions

被引：1

作者：

吴刚 ^{[1
]}

王小锋 ^{[2
]}

愈力 ^{[1
]}

张婷 ^{[1
]}

张敏 ^{[1
]}

机构：

[1] Department of Chemistry and Life Science,Chuzhou University

[2] College of Biochemical & Environmental Engineer,Xiaozhuang University

来源：

结构化学 | 2010年 / 29卷 / 09期

关键词：

hydrogen bond; C-H···π; interaction; cyclic voltammetry;

D O I：

10.14102/j.cnki.0254-5861.2010.09.014

中图分类号：

O621.13 [];

学科分类号：

070303 ; 081704 ;

摘要：

The title complex [Cu(L1)(L2)(H2O)]·H2O(1,HL1 = N-(imino(pyridin-2-yl)me-thyl)picolinamidine),HL2 = salicylic acid) has been obtained by volatilization method with L1 prepared from 2,4,6-tripyridyl-1,3,5-triazine in situ.1 was fully characterized by single-crystal X-ray diffraction,elemental analysis and FT-IR.This complex exhibits a three-dimensional frame-work constructed through hydrogen bonding and C-H···π stacking interactions.The cyclic voltametric behavior of complex 1 was also investigated.1 belongs to the monoclinic system,space group P21/c with a = 15.112(5),b = 7.115(2),c = 19.899(6) ,β = 112.32°,V = 1979.4(11) 3,Mr = 460.94,Dc = 1.540 g/cm3,F(000) = 948,μ = 1.146 mm-1,Z = 4,the final R = 0.0612 and wR = 0.1813 for 2510 observed reflections with I > 2σ(I).

引用

页码：1337 / 1342

页数：6

共 50 条

[41] N-H•••S AND C-H•••π HYDROGEN BONDING IN THIOUREA DERIVATIVES.
Raj, S. Shanmuga Sundara
Velmurugan, D.
Fun, Hoong Kun
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 1999, 55 : 384 - 384
[42] Graphane/Fluorographene Bilayer: Considerable C-H•••F-C Hydrogen Bonding and Effective Band Structure Engineering
Li, Yafei
Li, Fengyu
Chen, Zhongfang
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (27) : 11269 - 11275
[43] Intramolecular C-H•••O Hydrogen Bonding-Driven 1,2,3-Trazole Foldamers: Assessment of Intermolecular C-H•••X-(X=Cl, Br, I) and C-H•••N Hydrogen Bonding
Sun, Guangjun
Nie, Chengbin
Zhao, Xin
Li, Zhanting
CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2017, 37 (07) : 1757 - 1763
[44] Highly fluorinated naphthalenes and bifurcated C-H•••F-C hydrogen bonding
Loader, Jason R.
Libri, Stefano
Meijer, Anthony J. H. M.
Perutz, Robin N.
Brammer, Lee
CRYSTENGCOMM, 2014, 16 (41) : 9711 - 9720
[45] A new hydrogen bonding paradigm:: differing electrical interactions in C-H•••O and O-H•••O hydrogen bonds of formic acid.
Qian, WL
Krimm, S
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 224 : U499 - U499
[46] Evidence of C-H•••O Interactions in the Thiophene:Water Complex
Wasserman, Joshua G.
Murphy, Keshihito J.
Newby, Josh J.
JOURNAL OF PHYSICAL CHEMISTRY A, 2019, 123 (48): : 10406 - 10417
[47] Pressure induced C-H agostic interactions in a Uranium complex
Prescimone, Alessandro
Parsons, Simon
Arnold, Polly L.
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2016, 72 : S235 - S235
[48] Perturbing the structure of the 2-norbornyl cation through C-H•••N and C-H•••π interactions
Hong, Young J.
Tantillo, Dean J.
JOURNAL OF ORGANIC CHEMISTRY, 2007, 72 (23): : 8877 - 8881
[49] Characterization of C-H•••π interactions in the structure of the CHClF2-HCCH weakly bound complex
Sexton, John M.
Elliott, Ashley A.
Steber, Amanda L.
Peebles, Sean A.
Peebles, Rebecca A.
Neill, Justin L.
Muckle, Matt T.
Pate, Brooks H.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2010, 12 (42) : 14263 - 14270
[50] Vibrational Spectroscopy of hydrogen bonding:: Origin of the different behavior of the C-H•••O hydrogen bond
Qian, WL
Krimm, S
JOURNAL OF PHYSICAL CHEMISTRY A, 2002, 106 (28): : 6628 - 6636

← 1 2 3 4 5 →