An Extended Cu(Ⅱ) Complex Structure Sustained by Hydrogen Bonding and C-H…π Interactions

被引：1

作者：

吴刚 ^{[1
]}

王小锋 ^{[2
]}

愈力 ^{[1
]}

张婷 ^{[1
]}

张敏 ^{[1
]}

机构：

[1] Department of Chemistry and Life Science,Chuzhou University

[2] College of Biochemical & Environmental Engineer,Xiaozhuang University

来源：

结构化学 | 2010年 / 29卷 / 09期

关键词：

hydrogen bond; C-H···π; interaction; cyclic voltammetry;

D O I：

10.14102/j.cnki.0254-5861.2010.09.014

中图分类号：

O621.13 [];

学科分类号：

070303 ; 081704 ;

摘要：

The title complex [Cu(L1)(L2)(H2O)]·H2O(1,HL1 = N-(imino(pyridin-2-yl)me-thyl)picolinamidine),HL2 = salicylic acid) has been obtained by volatilization method with L1 prepared from 2,4,6-tripyridyl-1,3,5-triazine in situ.1 was fully characterized by single-crystal X-ray diffraction,elemental analysis and FT-IR.This complex exhibits a three-dimensional frame-work constructed through hydrogen bonding and C-H···π stacking interactions.The cyclic voltametric behavior of complex 1 was also investigated.1 belongs to the monoclinic system,space group P21/c with a = 15.112(5),b = 7.115(2),c = 19.899(6) ,β = 112.32°,V = 1979.4(11) 3,Mr = 460.94,Dc = 1.540 g/cm3,F(000) = 948,μ = 1.146 mm-1,Z = 4,the final R = 0.0612 and wR = 0.1813 for 2510 observed reflections with I > 2σ(I).

引用

页码：1337 / 1342

页数：6

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