Synthesis, Crystal Structure and Absolute Configuration of (+)-O-Phenyl Cyclophosphorodiamidate

被引：0
|
作者：
HE Kea ZHOU Zheng-Honga LI Kang-Yinga ZHAO Guo-Fenga TANG Chu-Chia② WANG Hong-Genb a (State Key Laboratory of Elemento-organic Chemistry
机构：
来源：
结构化学 | 2003年 / 06期
基金：
中国国家自然科学基金;
关键词：
O-phenyl cyclophosphorodiamidate; crystal structure; absolute configuration;
D O I：
10.14102/j.cnki.0254-5861.2003.06.015
中图分类号：
O625 [芳香族化合物];
学科分类号：
070303 ; 081704 ;
摘要：
The title compound, (+)-O-phenyl cyclophosphorodiamidate (C28H33N2O2P, Mr = 460.53), has been synthesized and characterized by 31P NMR, 1H NMR and elemental analysis. X-ray diffraction analysis at 273(2) K indicates that it belongs to orthorhombic system, space group P212121 with a = 11.518(4), b = 13.449(4), c = 16.539(5) ? V = 2562(1) 3, Z = 4, Dc = 1.194 g/cm3, F(000) = 984 and m(MoKa) = 0.134 mm-1. The structure parameters were refined by full-matrix least-squares on F2 to R = 0.0459 and wR = 0.0640. The flack x parameter is 0.03(10), and the absolute configuration of the phosphorus atom in the title compound is S.
引用
收藏
页码：705 / 709
页数：5
相关论文
共 50 条
  • [1] Synthesis, crystal structure and absolute configuration of (+)-O-phenyl cyclophosphorodiamidate
    He, K
    Zhou, ZH
    Li, KY
    Zhao, GF
    Tang, CC
    Wang, HG
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2003, 22 (06) : 705 - 709
  • [2] Synthesis, crystal structure and absolute configuration of (+)-O-naphthyl cyclophosphorodiamidate
    He, K
    Zhou, ZK
    Zhao, GF
    Wang, HG
    Tang, CC
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2003, 24 (11): : 1997 - 1999
  • [3] Crystal structure and absolute configuration of 28-O-acetylbetulin
    Suleimen, E. M.
    Van Hecke, K.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2016, 57 (01) : 206 - 208
  • [4] Crystal structure and absolute configuration of 28-O-acetylbetulin
    E. M. Suleimen
    K. Van Hecke
    Journal of Structural Chemistry, 2016, 57 : 206 - 208
  • [5] IMPROVED SYNTHESIS OF PHENYL BENZOHYDROXAMATE AND ITS CONVERSION TO PHENYL O-PHENYL BENZOHYDROXAMATE AND O-ETHYLBENZOHYDROXAMATE
    TAYLOR, EC
    KIENZLE, F
    JOURNAL OF ORGANIC CHEMISTRY, 1971, 36 (01): : 233 - &
  • [6] Synthesis, crystal structure and absolute configuration of (+)-(α-hydroxybenzyl)phenylphosphinic acid
    Cai, JX
    Zhou, ZH
    Tang, CC
    Wang, HG
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2002, 21 (04) : 368 - 370
  • [7] CRYSTAL-STRUCTURE AND ABSOLUTE-CONFIGURATION OF O,O-DIMETHYLIPECOSIDE
    ROBERTS, PJ
    ISAACS, NW
    ALLEN, FH
    MOTHERWE.WD
    KENNARD, O
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1974, B 30 (JAN15): : 133 - 139
  • [8] CRYSTAL STRUCTURE AND ABSOLUTE CONFIGURATION OF QINGHAOSU
    Qinghaosu Research Group Institute of Biophysics Academia Sinica
    ScienceinChina,SerA., 1980, Ser.A.1980 (03) : 380 - 396
  • [9] CRYSTAL STRUCTURE AND ABSOLUTE CONFIGURATION OF QINGHAOSU
    Qinghaosu Research Group Institute of Biophysics Academia Sinica
    Science China Mathematics, 1980, (03) : 380 - 396
  • [10] Synthesis,Crystal Structure and Absolute Configuration of (+)-(a-Hydroxybenzyl)phenylphosphinic acid
    CAI Jue-Xiao ZHOU Zheng-Hong TANG Chu-Chi② (State Key Laboratory of Elemento-Organic Chemistry
    结构化学, 2002, (04) : 368 - 370
12345