Synthesis, Crystal Structure and Absolute Configuration of (+)-O-Phenyl Cyclophosphorodiamidate

被引：0
|
作者：
HE Kea ZHOU Zheng-Honga LI Kang-Yinga ZHAO Guo-Fenga TANG Chu-Chia② WANG Hong-Genb a (State Key Laboratory of Elemento-organic Chemistry
机构：
来源：
结构化学 | 2003年 / 06期
基金：
中国国家自然科学基金;
关键词：
O-phenyl cyclophosphorodiamidate; crystal structure; absolute configuration;
D O I：
10.14102/j.cnki.0254-5861.2003.06.015
中图分类号：
O625 [芳香族化合物];
学科分类号：
070303 ; 081704 ;
摘要：
The title compound, (+)-O-phenyl cyclophosphorodiamidate (C28H33N2O2P, Mr = 460.53), has been synthesized and characterized by 31P NMR, 1H NMR and elemental analysis. X-ray diffraction analysis at 273(2) K indicates that it belongs to orthorhombic system, space group P212121 with a = 11.518(4), b = 13.449(4), c = 16.539(5) ? V = 2562(1) 3, Z = 4, Dc = 1.194 g/cm3, F(000) = 984 and m(MoKa) = 0.134 mm-1. The structure parameters were refined by full-matrix least-squares on F2 to R = 0.0459 and wR = 0.0640. The flack x parameter is 0.03(10), and the absolute configuration of the phosphorus atom in the title compound is S.
引用
收藏
页码：705 / 709
页数：5
相关论文
共 50 条
  • [31] ABSOLUTE CONFIGURATION AND CRYSTAL STRUCTURE OF ANTICHOLINERGIC DRUG DEXBENZETIMIDE
    SPEK, AL
    PEERDEMAN, AF
    VANWIJNG.I
    SOUDIJN, W
    NATURE, 1971, 232 (5312) : 575 - +
  • [32] CRYSTAL-STRUCTURE AND ABSOLUTE-CONFIGURATION OF BROMOISOTENULIN
    MAZHARUL.
    ROGERS, D
    CAUGHLAN, CN
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1974, (03): : 223 - 228
  • [33] CRYSTAL STRUCTURE OF CEDRYL CHROMATE AND ABSOLUTE CONFIGURATION OF (+)-CEDROL
    AMIRTHALINGAM, V
    GRANT, DF
    SENOL, A
    ACTA CRYSTALLOGRAPHICA SECTION A-CRYSTAL PHYSICS DIFFRACTION THEORETICAL AND GENERAL CRYSTALLOGRAPHY, 1969, A 25 : S129 - +
  • [34] CRYSTAL-STRUCTURE AND ABSOLUTE CONFIGURATION OF TRIPTYCENE DERIVATIVES
    SAKABE, N
    SAKABE, K
    OZEKIMIN.K
    KATAYAMA, C
    TANAKA, J
    ACTA CRYSTALLOGRAPHICA SECTION A, 1972, 28 : S28 - S29
  • [35] STRUCTURE, ABSOLUTE-CONFIGURATION AND SYNTHESIS OF OPHIOCARPINONE
    BHAKUNI, DS
    GUPTA, PK
    JOSHI, PP
    GUPTA, S
    INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 1982, 21 (05): : 389 - 392
  • [36] RETAMINE STRUCTURE SYNTHESIS ABSOLUTE CONFIGURATION AND CONFORMATION
    RIBAS, I
    CASTEDO, JL
    GARCIA, A
    TETRAHEDRON LETTERS, 1965, (36) : 3181 - &
  • [37] CRYSTAL-STRUCTURE AND ABSOLUTE-CONFIGURATION OF ALPHA-(1-PHENYLETHYLIMINO)BENZYL PHENYL KETONE
    FONSECA, I
    MARTINEZCARRERA, S
    GARCIABLANCO, S
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1979, 35 (NOV): : 2643 - 2646
  • [38] O-Phenyl (cyclohexylamido)(p-tolylamido)phosphinate
    Sabbaghi, Fahimeh
    Pourayoubi, Mehrdad
    Ahmadabad, Fatemeh Karimi
    Parvez, Masood
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O1502 - U1466
  • [39] Diphenoxybismuth(III)O-phenyl 4-methoxyphenylphosphonodithioate
    I. S. Nizamov
    A. V. Matseevskii
    E. S. Batyeva
    Russian Chemical Bulletin, 1998, 47 : 2049 - 2050
  • [40] Diphenoxybismuth(III) O-phenyl 4-methoxyphenylphosphonodithioate
    Nizamov, IS
    Matseevskii, AV
    Batyeva, ES
    RUSSIAN CHEMICAL BULLETIN, 1998, 47 (10) : 2049 - 2050
12345