Chitosan-immobilized Palladium Complex: a Green and Highly Active Heterogeneous Catalyst for Heck Reaction

被引:1
|
作者
Pu LIU
机构
关键词
Chitosan-immobilized palladium complex; green catalyst; Heck reaction;
D O I
暂无
中图分类号
O643.3 [催化];
学科分类号
081705 ;
摘要
A green heterogeneous catalyst for Heck reaction-chitosan-immobilized palladium complex was prepared. The catalyst exhibits high activity and stereoselectivity under the moderate reaction conditions. The catalyst can be separated easily from the reaction mixture and reused after washing. Under the suitable reaction conditions, the cross-coupling of iodobenzene (ArI) with acrylic acid (AA) or acrylate can be achieved 93.3% or 99% yield of trans-cinnamic acid or trans-cinnamic ester.
引用
收藏
页码:475 / 477
页数:3
相关论文
共 50 条
  • [41] Palladium bipyridyl complex anchored on nanosized MCM-41 as a highly efficient and recyclable catalyst for Heck reaction
    Tsai, FY
    Wu, CL
    Mou, CY
    Chao, MC
    Lin, HP
    Liu, ST
    TETRAHEDRON LETTERS, 2004, 45 (40) : 7503 - 7506
  • [42] 2-Iminopyridylpalladium dichloride as highly active catalyst for the Heck reaction
    Chen, Weixuan
    Xi, Chanjuan
    Yang, Ke
    APPLIED ORGANOMETALLIC CHEMISTRY, 2007, 21 (08) : 641 - 644
  • [43] Design of highly robust halloysite nanoclay supported palladium complex as a highly active heterogeneous catalyst for construction of biaryls
    Baran, Nuray Yilmaz
    Baran, Talat
    Mentes, Ayfer
    APPLIED CLAY SCIENCE, 2019, 181
  • [44] Sesbania gum xanthate supported palladium complex as an efficient catalyst for Heck reaction
    Zhang, Lei
    Zhang, Puyu
    Li, Xiang
    Cui, Yuanchen
    JOURNAL OF APPLIED POLYMER SCIENCE, 2007, 105 (04) : 2198 - 2202
  • [45] Mesoporous soot-supported palladium as a heterogeneous catalyst for the Heck reaction in ionic liquids
    Aslanov, Leonid A.
    Kabachii, Yury A.
    Kochev, Sergey Yu.
    Romanovsky, Boris V.
    Valletsky, Petr M.
    Volkov, Vladimir V.
    Yatsenko, Alexander V.
    Zakharov, Valery N.
    MENDELEEV COMMUNICATIONS, 2008, 18 (06) : 334 - 335
  • [46] Silicon Nanowires Supported Palladium Nanoparticles: An Efficient and Recyclable Heterogeneous Catalyst for Heck Reaction
    Liu, Li
    Shao, Mingwang
    Wang, Xiuhua
    ASIAN JOURNAL OF CHEMISTRY, 2011, 23 (07) : 3059 - 3062
  • [47] Heterogeneous Heck reaction in microemulsion with palladium supported Na-Y zeolites as catalyst
    Jiang, Jian-Zhong
    Cai, Chun
    JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY, 2006, 27 (08) : 1137 - 1140
  • [48] The fabrication of palladium-pyridyl complex multilayers and their application as a catalyst for the Heck reaction
    Gao, Shuiying
    Huang, Yuanbiao
    Cao, Minna
    Liu, Tian-fu
    Cao, Rong
    JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (41) : 16467 - 16472
  • [49] Konjac glucomannan supported palladium complex: An efficient and recyclable catalyst for Heck reaction
    Liu, Pu
    Yang, Yonghuan
    Liu, Ye
    Wang, Xiangyu
    REACTIVE & FUNCTIONAL POLYMERS, 2008, 68 (01): : 384 - 388
  • [50] First use of a palladium complex with a thiosemicarbazone ligand as catalyst precursor for the Heck reaction
    Kovala-Demertzi, D
    Yadav, PN
    Dernertzis, MA
    Jasiski, JP
    Andreadaki, FJ
    Kostas, ID
    TETRAHEDRON LETTERS, 2004, 45 (14) : 2923 - 2926