Chitosan-immobilized Palladium Complex: a Green and Highly Active Heterogeneous Catalyst for Heck Reaction

被引：1
|
作者：
Pu LIU
机构：
来源：
Chinese Chemical Letters | 2004年 / 04期
关键词：
Chitosan-immobilized palladium complex; green catalyst; Heck reaction;
D O I：
暂无
中图分类号：
O643.3 [催化];
学科分类号：
081705 ;
摘要：
A green heterogeneous catalyst for Heck reaction-chitosan-immobilized palladium complex was prepared. The catalyst exhibits high activity and stereoselectivity under the moderate reaction conditions. The catalyst can be separated easily from the reaction mixture and reused after washing. Under the suitable reaction conditions, the cross-coupling of iodobenzene (ArI) with acrylic acid (AA) or acrylate can be achieved 93.3% or 99% yield of trans-cinnamic acid or trans-cinnamic ester.
引用
收藏
页码：475 / 477
页数：3
相关论文
共 50 条
  • [31] Synthesis of a palladium phosphito pincer complex: A highly active catalyst for Heck couplings of disubstituted alkenes.
    Grause, C
    Morales, DM
    Jensen, CM
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1999, 218 : U896 - U896
  • [32] Heterogeneous catalysis by highly active supported Pd for the Heck reaction
    Huang, L.
    Tan, J.
    Chen, F. X.
    Ang, T. P.
    Wong, P. K.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006, 231
  • [33] Palladium Immobilized on 2,2′-Dipyridyl-Based Hypercrosslinked Polymers as a Heterogeneous Catalyst for Suzuki–Miyaura Reaction and Heck Reaction
    Cijie Liu
    Wei Xu
    Dexuan Xiang
    Qionglin Luo
    Shunqin Zeng
    Lijuan Zheng
    Yujie Tan
    Yuejun Ouyang
    Hongwei Lin
    Catalysis Letters, 2020, 150 : 2558 - 2565
  • [34] HETEROGENEOUS PALLADIUM CATALYSTS FOR THE HECK REACTION
    KIVIAHO, J
    HANAOKA, T
    KUBOTA, Y
    SUGI, Y
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1995, 101 (01) : 25 - 31
  • [35] Palladium nanoparticles embedded chitosan/poly(vinyl alcohol) composite nanofibers as an efficient and stable heterogeneous catalyst for Heck reaction
    Ye, Zeyu
    Zhang, Benben
    Shao, Linjun
    Xing, Guiying
    Qi, Chenze
    Tao, Hongyu
    JOURNAL OF APPLIED POLYMER SCIENCE, 2019, 136 (41)
  • [36] Palladium tetrazole-supported complex as an efficient catalyst for the Heck reaction
    He, Ying
    Cai, Chun
    TRANSITION METAL CHEMISTRY, 2011, 36 (01) : 113 - 117
  • [37] Palladium Immobilized on 2,2′-Dipyridyl-Based Hypercrosslinked Polymers as a Heterogeneous Catalyst for Suzuki-Miyaura Reaction and Heck Reaction
    Liu, Cijie
    Xu, Wei
    Xiang, Dexuan
    Luo, Qionglin
    Zeng, Shunqin
    Zheng, Lijuan
    Tan, Yujie
    Ouyang, Yuejun
    Lin, Hongwei
    CATALYSIS LETTERS, 2020, 150 (09) : 2558 - 2565
  • [38] O-Carboxymethyl Chitosan Supported Heterogeneous Palladium and Ni Catalysts for Heck Reaction
    Lv, Dongjun
    Zhang, Mingjie
    MOLECULES, 2017, 22 (01):
  • [39] A Highly Active Heterogeneous Palladium Catalyst Supported on a Synthetic Adsorbent
    Monguchi, Yasunari
    Fujita, Yuki
    Endo, Koichi
    Takao, Shinobu
    Yoshimura, Masatoshi
    Takagi, Yukio
    Maegawa, Tomohiro
    Sajiki, Hironao
    CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (04) : 834 - 837
  • [40] N-Allylation of amines with allyl acetates using chitosan-immobilized palladium
    Baig, R. B. Nasir
    Vaddula, Buchi R.
    Gonzalez, Michael A.
    Varma, Rajender S.
    RSC ADVANCES, 2014, 4 (18): : 9103 - 9106
12345