Synthesis and host-guest properties of pillar[6]arenes

被引：0
|
作者：
MEIER Herbert [1 ]
机构：
[1] Institute of Organic Chemistry,University of Mainz
来源：
Science China Chemistry | 2012年 / 02期
关键词：
calixarene; pillararene; FeCl; 3; supramolecular chemistry; host-guest property;
D O I：
暂无
中图分类号：
O621.3 [有机合成化学];
学科分类号：
070303 ; 081704 ;
摘要：
A facile method for the synthesis of pillar[6]arenes was developed.A series of pillar[6]arenes were prepared with FeCl 3 as catalyst and chloroform as solvent at room temperature in moderate yields(30%-40%).Their host-guest properties with n-cetyltrimethyl ammonium bromide were investigated by 1 HNMR.The results showed that high selectivity in the host-guest relationship became apparent between pillar[6]arenes and pillar[5]arenes based on the different size of the inner cavity.
引用
收藏
页码：223 / 228
页数：6
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