Synthesis and host-guest properties of pillar[6]arenes

被引：0

作者：

MEIER Herbert ^{[1
]}

机构：

[1] Institute of Organic Chemistry,University of Mainz

来源：

Science China Chemistry | 2012年 / 02期

关键词：

calixarene; pillararene; FeCl; 3; supramolecular chemistry; host-guest property;

D O I：

暂无

中图分类号：

O621.3 [有机合成化学];

学科分类号：

070303 ; 081704 ;

摘要：

A facile method for the synthesis of pillar[6]arenes was developed.A series of pillar[6]arenes were prepared with FeCl 3 as catalyst and chloroform as solvent at room temperature in moderate yields(30%-40%).Their host-guest properties with n-cetyltrimethyl ammonium bromide were investigated by 1 HNMR.The results showed that high selectivity in the host-guest relationship became apparent between pillar[6]arenes and pillar[5]arenes based on the different size of the inner cavity.

引用

页码：223 / 228

页数：6

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