SILICON-CONTAINING POLY(p-ARYLENE VINYLENE)S:SYNTHESIS AND PHOTOPHYSICS

被引:1
|
作者
李书宏 [1 ]
徐彩虹 [2 ]
机构
[1] Department of Chemistry,School of Science,Beijing Technology and Business University
[2] Institute of Chemistry,Chinese Academy of Sciences
基金
中国国家自然科学基金;
关键词
Poly(p-arylene vinylene)s(PAVs); Hydrosilylation reaction; Photophysics;
D O I
暂无
中图分类号
O634.41 [];
学科分类号
摘要
A series of new silicon-containing poly(p-arylene vinylene)s(PAVs)with anthracene units in the main chain were synthesized by hydrosilylation reaction.The introduction of organosilicon units improved the solubility of the polymers,and theπ-πconjugation of polymeric chains was interrupted.These polymers behaved as blue-green light emitters with their fluorescence maximum at 447—499 nm and quantum yields in the range of 0.28-0.30 in solution.
引用
收藏
页码:589 / 594
页数:6
相关论文
共 50 条
  • [31] Novel silicon-containing poly(p-phenylenevinylene)-related polymers: Synthesis and optical properties
    Kim, HK
    Ryu, MK
    Lee, SM
    MACROMOLECULES, 1997, 30 (04) : 1236 - 1239
  • [32] Photophysical properties of silicon-containing poly[salicylidene azomethine]s
    Alexandrova, E. L.
    Ivanov, A. G.
    Geller, N. M.
    Nadezhdina, L. B.
    Shamanin, V. V.
    SEMICONDUCTORS, 2008, 42 (10) : 1214 - 1218
  • [33] Silicon-containing aromatic poly(amide-imide)S
    Sava, Ion
    Hamciuc, Elena
    REVUE ROUMAINE DE CHIMIE, 2007, 52 (1-2) : 127 - 133
  • [34] New silicon-containing poly(imide-amide)s
    Hamciuc, E
    Bruma, M
    Schulz, B
    Köpnick, T
    HIGH PERFORMANCE POLYMERS, 2003, 15 (03) : 347 - 359
  • [35] Photophysical properties of silicon-containing poly[salicylidene azomethine]s
    E. L. Alexandrova
    A. G. Ivanov
    N. M. Geller
    L. B. Nadezhdina
    V. V. Shamanin
    Semiconductors, 2008, 42 : 1214 - 1218
  • [36] Synthesis of silicon-containing fullerenes
    Cao, BP
    Zhou, XH
    Shi, ZJ
    Gu, ZN
    Xiao, HZ
    Wang, JZ
    CHEMISTRY LETTERS, 1998, (08) : 735 - 736
  • [37] SYNTHESIS OF SILICON-CONTAINING CAGES
    DAMRAUER, R
    HANKIN, J
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1991, 202 : 55 - ORGN
  • [38] SYNTHESIS OF SILICON-CONTAINING EPOXYAMINOPROPIONITRILES
    SULTANOV, RA
    GASANOVA, FA
    SADYKHZA.SI
    JOURNAL OF GENERAL CHEMISTRY USSR, 1967, 37 (03): : 694 - &
  • [39] Electrochemical synthesis, characterization and photophysics of a poly (fluorenylene vinylene) derivative
    Gruber, J
    Li, RWC
    Aguiar, LHJMC
    Garcia, TL
    de Oliveira, HPM
    Atvars, TDZ
    Nogueira, AF
    SYNTHETIC METALS, 2006, 156 (2-4) : 104 - 109
  • [40] SYNTHESIS OF POLY(ARYLENE ETHER)S CONTAINING QUINOXALINE UNITS
    CONNELL, JW
    HERGENROTHER, PM
    POLYMER, 1992, 33 (17) : 3739 - 3743