SILICON-CONTAINING POLY(p-ARYLENE VINYLENE)S:SYNTHESIS AND PHOTOPHYSICS

被引:1
|
作者
李书宏 [1 ]
徐彩虹 [2 ]
机构
[1] Department of Chemistry,School of Science,Beijing Technology and Business University
[2] Institute of Chemistry,Chinese Academy of Sciences
基金
中国国家自然科学基金;
关键词
Poly(p-arylene vinylene)s(PAVs); Hydrosilylation reaction; Photophysics;
D O I
暂无
中图分类号
O634.41 [];
学科分类号
摘要
A series of new silicon-containing poly(p-arylene vinylene)s(PAVs)with anthracene units in the main chain were synthesized by hydrosilylation reaction.The introduction of organosilicon units improved the solubility of the polymers,and theπ-πconjugation of polymeric chains was interrupted.These polymers behaved as blue-green light emitters with their fluorescence maximum at 447—499 nm and quantum yields in the range of 0.28-0.30 in solution.
引用
收藏
页码:589 / 594
页数:6
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