Photoinduced C–H direct arylation of unactivated arenes

被引：0

作者：

Jian Kan ^{[1
]}

Shijun Huang ^{[1
]}

Huaiqing Zhao ^{[1
]}

Jin Lin ^{[1
]}

Weiping Su ^{[1
]}

机构：

[1] State Key Laboratory of Structural Chemistry

来源：

Science China(Chemistry) | 2015年 / 08期

基金：

中国国家自然科学基金;

关键词：

C–H bond activation; photoinduced; free radical; aryl iodide;

D O I：

暂无

中图分类号：

O621.25 [];

学科分类号：

070303 ; 081704 ;

摘要：

Two general protocols have been developed for the photoinduced,metal-free direct arylation of unactivated arenes with aryl iodide.Both methods gave good to excellent yields for most substrates.Notably,the C–F bond in method A and the C–F,C–Cl,and C–Br bonds in method B could survive the arylation reaction.These methods offered excellent options for syntheses of biaryls.

引用

页码：1329 / 1333

页数：5

共 50 条

[31] Direct arylation via cleavage of activated and unactivated C-H bonds
Miura, M
Nomura, M
CROSS-COUPLING REACTIONS: A PRACTICAL GUIDE, 2002, 219 : 211 - 241
[32] Direct C(sp2)-H alkylation of unactivated arenes enabled by photoinduced Pd catalysis (vol 11, 5266, 2020)
Kim, Daeun
Lee, Geun Seok
Kim, Dongwook
Hong, Soon Hyeok
NATURE COMMUNICATIONS, 2020, 11 (01)
[33] Direct C-H arylation of simple arenes: Ligand effect and mechanism
Hong, Soon Hyeok
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 254
[34] Sustainable protocols for direct C-H bond arylation of (hetero)arenes
Albano, Gianluigi
Punzi, Angela
Capozzi, Maria Annunziata M.
Farinola, Gianluca M.
GREEN CHEMISTRY, 2022, 24 (05) : 1809 - 1894
[35] Developments in Direct C?H Arylation of (Hetero)Arenes under Microwave Irradiation
Sharma, Abhishek
Vacchani, Dipak
Van der Eycken, Erik
CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (04) : 1158 - 1168
[36] Palladium-catalyzed C-H functionalization of pyridine N-oxides:: Highly selective alkenylation and direct arylation with unactivated arenes
Cho, Seung Hwan
Hwang, Seung Jun
Chang, Sukbok
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (29) : 9254 - +
[37] Transition-Metal-Free C-H Arylation of Unactivated Arenes with 8-Hydroxyquinoline as a Promoter
Zheng, Xuehua
Wu, Xu-Nian
Chen, Jing-Yi
Luo, Hai-Bin
Wu, Deyan
Wu, Yinuo
SYNTHESIS-STUTTGART, 2018, 50 (08): : 1721 - 1727
[38] Formal C-H Carboxylation of Unactivated Arenes
Gevorgyan, Ashot
Hopmann, Kathrin H.
Bayer, Annette
CHEMISTRY-A EUROPEAN JOURNAL, 2020, 26 (27) : 6064 - 6069
[39] Transition-Metal-Free Glucose-Derived Carbonaceous Catalyst Catalyzes Direct C-H Arylation of Unactivated Arenes with Aryl Halides
Jori, Popat K.
Jadhav, Vrushali H.
CHEMISTRYSELECT, 2019, 4 (17): : 4848 - 4853
[40] Direct C-H Bond Arylation of (Hetero)arenes with Aryl and Heteroarylboronic Acids
Guchhait, Sankar K.
Kashyap, Maneesh
Saraf, Shuddham
SYNTHESIS-STUTTGART, 2010, (07): : 1166 - 1170

← 1 2 3 4 5 →