Photoinduced C–H direct arylation of unactivated arenes

被引：0

作者：

Jian Kan ^{[1
]}

Shijun Huang ^{[1
]}

Huaiqing Zhao ^{[1
]}

Jin Lin ^{[1
]}

Weiping Su ^{[1
]}

机构：

[1] State Key Laboratory of Structural Chemistry

来源：

Science China(Chemistry) | 2015年 / 08期

基金：

中国国家自然科学基金;

关键词：

C–H bond activation; photoinduced; free radical; aryl iodide;

D O I：

暂无

中图分类号：

O621.25 [];

学科分类号：

070303 ; 081704 ;

摘要：

Two general protocols have been developed for the photoinduced,metal-free direct arylation of unactivated arenes with aryl iodide.Both methods gave good to excellent yields for most substrates.Notably,the C–F bond in method A and the C–F,C–Cl,and C–Br bonds in method B could survive the arylation reaction.These methods offered excellent options for syntheses of biaryls.

引用

页码：1329 / 1333

页数：5

共 50 条

[21] Author Correction: Direct C(sp2)–H alkylation of unactivated arenes enabled by photoinduced Pd catalysis
Daeun Kim
Geun Seok Lee
Dongwook Kim
Soon Hyeok Hong
Nature Communications, 11
[22] Proline Catalyzes Direct C-H Arylations of Unactivated Arenes
Tanimoro, Kouichi
Ueno, Minoru
Takeda, Kazutaka
Kirihata, Mitsunori
Tanimori, Shinji
JOURNAL OF ORGANIC CHEMISTRY, 2012, 77 (18): : 7844 - 7849
[23] Cobalt-Catalyzed Direct Arylation of Unactivated Arenes with Aryl Halides
Liu, Wei
Cao, Hao
Xin, Jie
Jin, Liqun
Lei, Aiwen
CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (13) : 3588 - 3592
[24] Palladium-catalyzed direct arylation of benzoxazoles with unactivated simple arenes
Wu, Ge
Zhou, Jun
Zhang, Min
Hu, Peng
Su, Weiping
CHEMICAL COMMUNICATIONS, 2012, 48 (71) : 8964 - 8966
[25] Iron-Catalyzed Direct Arylation of Unactivated Arenes with Aryl Halides
Liu, Wei
Cao, Hao
Lei, Aiwen
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (11) : 2004 - 2008
[26] Direct intramolecular arylation of unactivated arenes:: application to the synthesis of aporphine alkaloids
Lafrance, M
Blaquière, N
Fagnou, K
CHEMICAL COMMUNICATIONS, 2004, (24) : 2874 - 2875
[27] Polyfunctional Conjugated Microporous Polymers for Applications in Direct C-H Arylation of Unactivated Arenes and Aqueous Adsorption of Aromatic Amines
Luo Kexin
Su Qing
Ju Pengyao
Li Xiaodong
Liu Ziqian
Sun Xiaoman
Li Guanghua
Wu Qiaolin
CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 2020, 36 (06) : 1302 - 1309
[28] Polyfunctional Conjugated Microporous Polymers for Applications in Direct C-H Arylation of Unactivated Arenes and Aqueous Adsorption of Aromatic Amines
Kexin Luo
Qing Su
Pengyao Ju
Xiaodong Li
Ziqian Liu
Xiaoman Sun
Guanghua Li
Qiaolin Wu
Chemical Research in Chinese Universities, 2020, 36 : 1302 - 1309
[29] Iridium-Promoted, Palladium-Catalyzed Direct Arylation of Unactivated Arenes
Durak, Landon J.
Lewis, Jared C.
ORGANOMETALLICS, 2014, 33 (03) : 620 - 623
[30] Ir-promoted, Pd-catalyzed direct arylation of unactivated arenes
Durak, Landon J.
Lewis, Jared C.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 247

← 1 2 3 4 5 →