Photoinduced C–H direct arylation of unactivated arenes

被引：0
|
作者：
Jian Kan [1 ]
Shijun Huang [1 ]
Huaiqing Zhao [1 ]
Jin Lin [1 ]
Weiping Su [1 ]
机构：
[1] State Key Laboratory of Structural Chemistry
来源：
Science China Chemistry | 2015年 / 08期
基金：
中国国家自然科学基金;
关键词：
C–H bond activation; photoinduced; free radical; aryl iodide;
D O I：
暂无
中图分类号：
O621.25 [];
学科分类号：
070303 ; 081704 ;
摘要：
Two general protocols have been developed for the photoinduced,metal-free direct arylation of unactivated arenes with aryl iodide.Both methods gave good to excellent yields for most substrates.Notably,the C–F bond in method A and the C–F,C–Cl,and C–Br bonds in method B could survive the arylation reaction.These methods offered excellent options for syntheses of biaryls.
引用
收藏
页码：1329 / 1333
页数：5
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