Tandem Reaction of Deprotonation-Oxidation-Wittig Reaction: Stereoselective Synthesis of (E)-α,β-Unsaturated Enoates

被引：0
|
作者：
黄志真
孙若君
机构：
来源：
Chinese Journal of Chemistry | 2002年 / 11期
关键词：
phosphonium or arsonium salt; alcohol; ylide; α; β-unsaturated enoate; synthesis; deprotonation; oxidation; Wittig reaction; tandem reaction;
D O I：
暂无
中图分类号：
O623 [脂肪族化合物（无环化合物）];
学科分类号：
摘要：
Phosphonium or arsonium salt with primary alcohol can undergo the tandem reaction of deprotonation-oxidation-Wittig reaction in the presence of sodium hydroxide and manganese dioxide, providing a general and efficient method for the stereoselective synthesis of (E)-α,β-unsaturated enoates.
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页码：1460 / 1462 +1136
页数：4
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