A new member of the calix[4]crown family:Facile synthesis and characterization of a calix[4]crown-9 cone conformer

被引:0
|
作者
Hao Hui Zhou Xian Mei Shang Zhi Luo Yu Xiang Xia Jun Luo~* Guang Ya Xiang Tongji School of Pharmacy
机构
关键词
Calix[4]crown-9; Cone conformation; Synthesis; Intramolecular cyclization;
D O I
暂无
中图分类号
O621.3 [有机合成化学];
学科分类号
摘要
25,27-Dipropoxy-p-tert-butylcalix[4]crown-9 cone conformer 5 was readily synthesized via an intramolecular cyclization strategy in good yields.The structures of all the new compounds involved were confirmed by NMR,ESI-MS and elemental analyses.All of them were proved to be in the cone conformation.
引用
收藏
页码:143 / 146
页数:4
相关论文
共 50 条
  • [41] Synthesis and Complexation Properties of Novel Chiral Calix[4]-1,3-aza-crown and Calix[4]arene Hydrazone Derivative
    Yang Fa-fu
    Huang Zhi-sheng
    Guo Hong-yu
    Hong Bi-qiong
    Zhang Xiao-yi
    CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 2010, 26 (04) : 546 - 549
  • [42] New calix[4]crown diacylamides with fluorescent response to complexation with metal ions
    He, YB
    Huang, H
    Meng, LZ
    Wu, CT
    Yu, TX
    CHEMISTRY LETTERS, 1999, (12) : 1329 - 1330
  • [43] Synthesis and Complexation Properties of Novel Chiral Calix[4]-1,3-aza-crown and Calix[4]arene Hydrazone Derivative
    YANG Fa-fu~(1
    2.Fujian Key Laboratory of Polymer Materials
    Chemical Research in Chinese Universities, 2010, 26 (04) : 546 - 549
  • [44] Selective O-Alkylation of the Crown Conformer of Tetra(4-hydroxyphenyl) calix[4] resorcinarene to the Corresponding Tetraalkyl Ether
    Castillo-Aguirre, Alver
    Rivera-Monroy, Zuly
    Maldonado, Mauricio
    MOLECULES, 2017, 22 (10)
  • [45] Chiral Molecular Cavities of Calix[4]Crown on Au(111)
    Pan, Ge-Bo
    Luo, Jun
    Deng, Qi-Yu
    Wan, Li-Jun
    JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2008, 8 (11) : 5702 - 5707
  • [46] Synthesis and metal ion extraction of cone di-ionizable calix[4]arene-crown-7 ligands
    Kang, Dong Eun
    Crawford, Jennifer D.
    Bartsch, Richard A.
    JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 2015, 83 (1-2) : 37 - 43
  • [47] Synthesis and metal ion extraction of cone di-ionizable calix[4]arene-crown-7 ligands
    Dong Eun Kang
    Jennifer D. Crawford
    Richard A. Bartsch
    Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2015, 83 : 37 - 43
  • [48] Synthesis of a new calix[4]crown-5-azacrown-5 dimeric nano-tube
    Kim, SK
    Kim, SH
    Kwon, SG
    Lee, EH
    Lee, SH
    Kim, JS
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2004, 25 (08): : 1244 - 1246
  • [49] Synthesis of calix[4]arene-crown-6 with alkoxysilyl-containing substituents
    E. A. Alekseeva
    S. S. Basok
    A. V. Mazepa
    A. I. Gren’
    Russian Journal of Organic Chemistry, 2008, 44 : 348 - 352
  • [50] KF and CsF Recognition and Extraction by a Calix[4]crown-5 Strapped Calix[4]pyrrole Multitopic Receptor
    Kim, Sung Kuk
    Lynch, Vincent M.
    Young, Neil J.
    Hay, Benjamin P.
    Lee, Chang-Hee
    Kim, Jong Seung
    Moyer, Bruce A.
    Sessler, Jonathan L.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (51) : 20837 - 20843