A new member of the calix[4]crown family:Facile synthesis and characterization of a calix[4]crown-9 cone conformer

被引:0
|
作者
Hao Hui Zhou Xian Mei Shang Zhi Luo Yu Xiang Xia Jun Luo~* Guang Ya Xiang Tongji School of Pharmacy
机构
关键词
Calix[4]crown-9; Cone conformation; Synthesis; Intramolecular cyclization;
D O I
暂无
中图分类号
O621.3 [有机合成化学];
学科分类号
摘要
25,27-Dipropoxy-p-tert-butylcalix[4]crown-9 cone conformer 5 was readily synthesized via an intramolecular cyclization strategy in good yields.The structures of all the new compounds involved were confirmed by NMR,ESI-MS and elemental analyses.All of them were proved to be in the cone conformation.
引用
收藏
页码:143 / 146
页数:4
相关论文
共 50 条
  • [21] An inherently chiral calix[4]crown carboxylic acid in the partial cone conformation
    Jiao Shi
    Si-Zhe Li
    Yu-Xiang Xia
    Xiao-Gang Wang
    Jun Luo
    Qian Wan
    Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2013, 77 : 327 - 335
  • [22] Synthesis of Novel Chiral Calix[4]crown: Lariat Calix[4]-1,3-aza-crown with Chiral Amino Acid Group as Branched Chain
    Yang, Fafu
    Hong, Biqiong
    Guo, Hongyu
    Huang, Zhisheng
    Zhang, Xiaoyi
    LETTERS IN ORGANIC CHEMISTRY, 2011, 8 (05) : 358 - 360
  • [23] Studies on synthesis and complexation properties of calix[4] monothia crown-5 and calix[4]monoselenacrown-5
    Chen, YY
    Chen, YK
    Lu, XR
    Gong, SL
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 1999, 20 (10): : 1570 - 1573
  • [24] Synthesis and properties of calix[4]crown-6 functionalized polymers
    Su-Han Kim
    Chil-Won Lee
    Young-Min Jeon
    Myoung-Seon Gong
    Macromolecular Research, 2005, 13 : 141 - 146
  • [25] Synthesis and properties of calix[4]crown-6 functionalized polymers
    Kim, SH
    Lee, CW
    Jeon, YM
    Gong, MS
    MACROMOLECULAR RESEARCH, 2005, 13 (02) : 141 - 146
  • [26] Synthesis and complexing properties of methylated calix[4](aza)crown derivatives
    Oueslati, I
    Abidi, R
    Thuéry, P
    Nierlich, M
    Asfari, Z
    Harrowfield, J
    Vicens, J
    TETRAHEDRON LETTERS, 2000, 41 (43) : 8263 - 8267
  • [27] Potassium sensing calix[4]arene crown ethers
    Kim, JS
    Lee, WK
    Ra, DY
    Lee, YI
    Choi, WK
    Lee, KW
    Oh, WZ
    MICROCHEMICAL JOURNAL, 1998, 59 (03) : 464 - 471
  • [28] Calix[4]crown in dual sensing functions with FRET
    Lee, SH
    Kim, SK
    Bok, JH
    Lee, SH
    Yoon, J
    Lee, K
    Kim, JS
    TETRAHEDRON LETTERS, 2005, 46 (47) : 8163 - 8167
  • [29] MOLECULAR RECOGNITION OF BUTYLAMINES BY CALIX [4]-CROWN ETHERS
    SONG, BM
    CHANG, SK
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 1993, 14 (05) : 540 - 542
  • [30] Enantioselective recognition of an inherently chiral calix[4] arene crown-6 carboxylic acid cone conformer towards chiral aminoalcohols
    Yang, Ke
    Li, Si-Zhe
    Wang, Yin-Hu
    Zhang, Wen-Zhen
    Xu, Zhan-Hui
    Zhou, Xiang-Yong
    Zhu, Rong-Xiu
    Luo, Jun
    Wan, Qian
    RSC ADVANCES, 2014, 4 (13) : 6517 - 6526