STUDIES ON THE SOLID STATE REACTIONS OF COORDINATION COM POUNDS（ⅩⅩⅩⅩⅥ）——Solid State Synthesis and Crystal Structure of Cluster Compound{Ag3WS3Br}（PPh3）3S·H2O

被引：0
|
作者：
Lang Jian-Ping Zhu Hui-Zhen Xin Xin-QuanCoordination Chemistry Institute
机构：
来源：
结构化学 | 1992年 / 04期
关键词：
Ag; H2O; PPh3)3S; Solid State Synthesis and Crystal Structure of Cluster Compound{Ag3WS3Br; WS; COM;
D O I：
10.14102/j.cnki.0254-5861.1992.04.009
中图分类号：
学科分类号：
摘要：
The title compound {Ag3WS3Br} (PPh3)3S ·H2O was obtained by a solid state reaction of (NH4)2WS4, AgBr and Ppha under the protection of N2 atom-sphere at 95℃. The crystal data are: Mr=1520. 0, triclinic, P1, a = 12. 129(5) , b = 13.340(0), c=20.228(6)(?), *=74. 48(3), β=87. 17(8) ,γ= 63. 53(3)°, V = 2813. 98(?)3, Z = 2, Dc=1.772g/cm3, μ = 40. 67cm-1, F(000) = 1475. 79. The final R is 0.056 for 6701 refections(I≥1. 5σ(I)). The title compound is the first example of W -Ag-S cluster compound with a cubane-like structure. The average distance of W-Ag is 2. 986(?).
引用
收藏
页码：274 / 278
页数：5
相关论文
共 50 条
  • [41] SOLID-STATE SYNTHESIS, CRYSTAL-STRUCTURE, AND EFFECTIVE 3RD-ORDER NONLINEAR-OPTICAL PROPERTIES OF (NET(4))(3)[MOOS3CU3BR3(MU(2)-BR)]CENTER-DOT-2H(2)O
    SHI, S
    CHEN, ZR
    HOU, HW
    XIN, XQ
    YU, KB
    CHEMISTRY OF MATERIALS, 1995, 7 (08) : 1519 - 1524
  • [42] Synthesis and structural characterization of silver(I) and gold(I) complexes with 2-mercaptonicotinic acid (H2mna) and triphenylphosphine ligands, and their antimicrobial activities.: Crystal structures of monomeric, 3-and 4-coordinate silver(I) complexes [Ag(Hmna)(PPh3)2] and [Ag(Hmna)(PPh3)3] in the solid state
    Nomiya, K
    Noguchi, R
    Shigeta, T
    Kondoh, Y
    Tsuda, K
    Ohsawa, K
    Chikaraishi-Kasuga, N
    Oda, M
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2000, 73 (05) : 1143 - 1152
  • [43] Synthesis and Crystal Structure of Copper (Ⅱ) Compound with 3,3'-Azobispyridine Ligand [Cu(NO3)2(H2O)2(3,3'azpy)2]
    LI Bao-Longa LANG Jian-Pinga WANG Shou-Wua XU Zhengb CHEN Jiu-Tongc a (Department of Chemistry and Chemical Engineering
    结构化学, 2003, (01) : 17 - 20
  • [44] Synthesis, solid-state structure and multinuclear NMR studies of the new polyhydrido iridium carbonyl cluster Ir4H4(μ-H)4(CO)4(PPh3)4
    Garlaschelli, L
    Greco, F
    Peli, G
    Manassero, M
    Sansoni, M
    Gobetto, R
    Salassa, L
    Della Pergola, R
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2003, (11) : 2108 - 2112
  • [45] Crystal structure, infrared, and solid state CP MAS NMR characterization of [(PPh3)2AgO2CH] and of [(PPh3)2AgO2CH]·2HCO2H, a complex of the H-bonded [H2(HCO2)3]- species
    Bowmaker, G.A.
    Hanna, J.V.
    Healy, P.C.
    Millar, G.J.
    Skelton, B.W.
    White, A.H.
    Journal of Physical Chemistry, 1995, 99 (12):
  • [46] SYNTHESIS AND CRYSTAL STRUCTURE OF THE TRINUCLEAR MOLYBDENUM CLUSTER WITH A LOOSE COORDINATION {Mo3(μ3-S)(μ-S)3[μ-S2P(OEt)2][S2P(OEt)2]3(H2O)}
    林贤梯
    林玉辉
    黄金陵
    黄建全
    Science Bulletin, 1987, (12) : 810 - 815
  • [47] THE SYNTHESIS AND CRYSTAL-STRUCTURE OF A NOVEL CUBANE-LIKE COMPLEX OF THE MO-AG-S SERIES - (MOAG3S3CL)(PPH3)3O
    WU, JH
    ZHU, NY
    DU, SW
    WU, XT
    LU, JX
    POLYHEDRON, 1992, 11 (10) : 1201 - 1204
  • [48] The solid state reaction between RhX(PPh3)3 and (η5-C5H4Me) W(CO)3X (X = Cl, Br, I)
    Eke, UB
    Coville, NJ
    INORGANIC CHEMISTRY COMMUNICATIONS, 2000, 3 (07) : 368 - 370
  • [49] SYNTHESIS AND CRYSTAL-STRUCTURE OF W2S4BR2(PPH3)2.C6H6
    FEDIN, VP
    MIRONOV, YV
    VIROVETS, AV
    PODBEREZSKAYA, NV
    FEDOROV, VY
    INORGANICA CHIMICA ACTA, 1990, 171 (02) : 199 - 203
  • [50] Solid state photoluminescence studies of [EuLnH2(NO3)3](H2O)x macrocyclic complexes with Schiff base ligands
    de Santana, Ricardo C.
    Fuentealba, Pablo A.
    Maia, Lauro J. Q.
    Paredes-Garcia, Veronica
    Aravena, Daniel
    Venegas-Yazigi, Diego
    Manzur, Jorge
    Spodine, Evgenia
    JOURNAL OF LUMINESCENCE, 2018, 203 : 7 - 15
12345