THE SYNTHESIS AND CRYSTAL-STRUCTURE OF A NOVEL CUBANE-LIKE COMPLEX OF THE MO-AG-S SERIES - (MOAG3S3CL)(PPH3)3O

被引：0

作者：

WU, JH ^{[1
]}

ZHU, NY ^{[1
]}

DU, SW ^{[1
]}

WU, XT ^{[1
]}

LU, JX ^{[1
]}

机构：

[1] CHINESE ACAD SCI,FUJIAN INST RES STRUCT MATTER,FUZHOU LAB STRUCT CHEM,FUJIAN 350002,PEOPLES R CHINA

来源：

POLYHEDRON | 1992年 / 11卷 / 10期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel Mo-Ag-S cubane-like complex, {MoAg3S3Cl}(PPh3)3O, has been synthesized from AgCl, PPh3 and Mo2O2S(S2)42- in appropriate conditions, and its X-ray crystal structure determined. The complex comprises one cubane-like cluster core {MoAg3S3Cl}2+, three PPh3 ligands attached to each silver atom and one terminal oxo ligand attached to the molybdenum atom [1.67(1) angstrom]. The mean distance of the molybdenum and silver atoms is 2.980(2) angstrom, which is too long to effectively bond. The bond lengths of the three Ag-Cl bonds are in the same range and average to 2.810(4) angstrom.

引用

页码：1201 / 1204

页数：4

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