Supramolecular and electrical properties of ruthenium-based organometallic gels

被引:0
|
作者
Eryilmaz, Ilknur Hatice [1 ]
Gallonde, William [2 ]
Caytan, Elsa [2 ]
Jeannin, Olivier [2 ]
Camerel, Franck [2 ]
Rigaut, Stephane [2 ]
Galangau, Olivier [2 ]
Orgiu, Emanuele [1 ]
机构
[1] Inst Natl Rech Sci, Ctr Energie Mat Telecommun, 1650 Blvd Lionel-Boulet, Varennes, PQ J3X 1P7, Canada
[2] Univ Rennes, ISCR Inst Sci Chim Rennes, CNRS, UMR 6226, F-35000 Rennes, France
基金
加拿大自然科学与工程研究理事会;
关键词
POLYMERS; PI; CHEMISTRY; GENERATION; COMPLEXES; GELATORS; SENSOR; METAL;
D O I
10.1039/d4tc04486j
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A novel organometallic gel whose molecular building block contains either one (Ru1) or two Ru (Ru2) atoms is presented, and its supramolecular properties in solution have been investigated. Its electrical characterization revealed that when Ru1 is used to form an organometallic gel, such a gel becomes highly sensitive to the presence of a common organic solvent, while when a Ru2 gel is employed the solvent modified electrical performances are preserved over days.
引用
收藏
页码:7393 / 7401
页数:9
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