Electrochemical Oxidative Hydroxychalcogenation of Olefins with Disulfides/Thiols/Diselenides and H2O as Nucleophilic Oxygen Sources

被引：0
|
作者：
Li, Wenxue [1 ]
Li, Junwu [1 ]
Sun, Fengkai [1 ]
Miao, Man [1 ]
Lan, Xiao-Bing [1 ]
Yu, Jian-Qiang [1 ]
Liu, Pengpeng [1 ]
Li, Houyuan [1 ]
Wang, Rui [1 ]
Zhang, Jian [1 ,2 ]
An, Zhenyu [1 ]
机构：
[1] Ningxia Med Univ, Peptide & Prot Drug Res Ctr, Key Lab Protect Dev & Utilizat Med Resources Liupa, Sch Pharm,Minist educ, Yinchuan 750004, Peoples R China
[2] Shanghai Jiao Tong Univ, Med Chem & Bioinformat Ctr, Sch Med, Shanghai 200025, Peoples R China
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2025年 / 28卷 / 07期
关键词：
Electrochemistry; Olefins; <italic>beta</italic>-hydroxyselenide; ALKENES; OXYSULFENYLATION; SULFOXIDES; SULFIDES; STYRENES; DESIGN; THIOLS;
D O I：
10.1002/ejoc.202401226
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A direct electrochemical redox reaction of olefins and disulfides/thiols/diselenides without external oxidants has been developed, which includes the hydroxychalcogenation of olefins. This procedure exhibited good functional group tolerance, and a series of beta-hydroxysulfide/beta-hydroxyselenide derivatives were obtained in moderate to good yields. Mechanistic studies and cyclic voltammetry were also conducted to elucidate the reaction process.
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页数：5
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