Electrochemical Oxidative Hydroxychalcogenation of Olefins with Disulfides/Thiols/Diselenides and H2O as Nucleophilic Oxygen Sources

被引：0

作者：

Li, Wenxue ^{[1
]}

Li, Junwu ^{[1
]}

Sun, Fengkai ^{[1
]}

Miao, Man ^{[1
]}

Lan, Xiao-Bing ^{[1
]}

Yu, Jian-Qiang ^{[1
]}

Liu, Pengpeng ^{[1
]}

Li, Houyuan ^{[1
]}

Wang, Rui ^{[1
]}

Zhang, Jian ^{[1
,2
]}

An, Zhenyu ^{[1
]}

机构：

[1] Ningxia Med Univ, Peptide & Prot Drug Res Ctr, Key Lab Protect Dev & Utilizat Med Resources Liupa, Sch Pharm,Minist educ, Yinchuan 750004, Peoples R China

[2] Shanghai Jiao Tong Univ, Med Chem & Bioinformat Ctr, Sch Med, Shanghai 200025, Peoples R China

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2025年 / 28卷 / 07期

关键词：

Electrochemistry; Olefins; <italic>beta</italic>-hydroxyselenide; ALKENES; OXYSULFENYLATION; SULFOXIDES; SULFIDES; STYRENES; DESIGN; THIOLS;

D O I：

10.1002/ejoc.202401226

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A direct electrochemical redox reaction of olefins and disulfides/thiols/diselenides without external oxidants has been developed, which includes the hydroxychalcogenation of olefins. This procedure exhibited good functional group tolerance, and a series of beta-hydroxysulfide/beta-hydroxyselenide derivatives were obtained in moderate to good yields. Mechanistic studies and cyclic voltammetry were also conducted to elucidate the reaction process.

引用

页数：5

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