Synthesis of β-Hydroxyselenides via Electrochemical Hydroxyselenenylation of Alkenes with Diselenides and H2O

被引：3
|
作者：
Li, Weiwei [1 ,2 ]
Hu, Yingyuan [3 ]
Hou, Junsheng [1 ,2 ]
Li, Jiaojiao [1 ,2 ]
Zhang, Xinxin [1 ,2 ]
Li, Jinxu [1 ,2 ]
Wang, Huijiao [1 ,2 ]
Liu, Qiang [1 ,2 ]
机构：
[1] Jiangsu Ocean Univ, Sch Pharm, Jiangsu, 222005, Peoples R China
[2] Jiangsu Ocean Univ, Jiangsu Key Lab Marine Pharmaceut Cpd Screening, Lianyungang 222005, Jiangsu, Peoples R China
[3] Suzhou Univ Sci & Technol, Sch Chem & Life Sci, Suzhou 215009, Jiangsu, Peoples R China
来源：
CHEMISTRYSELECT | 2024年 / 9卷 / 05期
关键词：
beta-hydroxyselenides; diselenides; alkenes; external oxidant-free; electrochemical hydroxyselenenylation; TRANSITION-METAL-FREE; ONE-POT SYNTHESIS; OXIDANT; OLEFINS; BENZENESELENOL; CYCLIZATION; ALKYNES;
D O I：
10.1002/slct.202304333
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A practical electrochemical method for the synthesis of beta-hydroxyselenides has been developed under an external oxidant-free condition at room temperature under air from alkenes with diselenides and H2O. A radical mechanism is proposed for this transformation and the gram-scale reactions demonstrate the practicability of this reaction.
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页数：5
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