N-Heterocyclic Carbene Catalysis for Polycyclic Benzazepines Assembly: Regioselective Intramolecular Tandem Radical Cyclization

被引：2
|
作者：
Feng, Zhiming [1 ]
Wu, Lili [1 ]
Zhou, Cong-Ying [1 ]
Wang, Chengming [1 ]
机构：
[1] Jinan Univ, Coll Chem & Mat Sci, Guangzhou 511443, Guangdong, Peoples R China
来源：
ORGANIC LETTERS | 2024年 / 26卷 / 42期
关键词：
D O I：
10.1021/acs.orglett.4c03303
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A variety of polycyclic benzazepines were rapidly constructed by NHC-catalyzed regioselective redox-neutral intramolecular tandem cyclization. Initial mechanistic studies revealed that a SET radical process was possibly involved.
引用
收藏
页码：9068 / 9072
页数：5
相关论文
共 50 条
  • [41] N-heterocyclic carbene-catalyzed radical reactions
    Kun-Quan Chen
    He Sheng
    Qiang Liu
    Pan-Lin Shao
    Xiang-Yu Chen
    Science China(Chemistry), 2021, 64 (01) : 7 - 16
  • [42] N-heterocyclic carbene-catalyzed radical reactions
    Chen, Kun-Quan
    Sheng, He
    Liu, Qiang
    Shao, Pan-Lin
    Chen, Xiang-Yu
    SCIENCE CHINA-CHEMISTRY, 2021, 64 (01) : 7 - 16
  • [43] N-heterocyclic carbene-catalyzed radical reactions
    Kun-Quan Chen
    He Sheng
    Qiang Liu
    Pan-Lin Shao
    Xiang-Yu Chen
    Science China Chemistry, 2021, 64 : 7 - 16
  • [44] N-Heterocyclic Carbene Catalyzed Intramolecular Acylation of Allylic Electrophiles
    Zhao, Ming
    Yang, Hui
    Li, Miao-Miao
    Chen, Jie
    Zhou, Ling
    ORGANIC LETTERS, 2014, 16 (11) : 2904 - 2907
  • [45] N-Heterocyclic Carbene and Manganese Synergistic Catalysis: A Three-Component Radical Acylmonofluoroalkylation of Alkenes
    Liang, Feng
    Chen, Ning
    Cheng, Keguang
    Wang, Quande
    ORGANIC LETTERS, 2023, 25 (45) : 8168 - 8172
  • [46] Asymmetric synthesis of atropisomers enabled by N-heterocyclic carbene catalysis
    Feng, Jie
    Du, Ding
    TETRAHEDRON, 2021, 100
  • [47] Iminoacylation of Alkenes via Photoredox N-Heterocyclic Carbene Catalysis
    Dong, Yi-Xiong
    Zhang, Chun-Lin
    Gao, Zhong-Hua
    Ye, Song
    ORGANIC LETTERS, 2023, : 855 - 860
  • [48] Recent advances in nickel N-heterocyclic carbene chemistry and catalysis
    Chetcuti, Michael J.
    Ritleng, Vincent
    Oertel, Anna M.
    Hernion, Mickaeel
    Veiros, Luis F.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 244
  • [49] Enantioselective Synthesis of δ-Carbolinones via N-Heterocyclic Carbene Catalysis
    Zhang, Simiao
    Lin, Chen
    Liu, Chaolei
    Du, Ding
    JOURNAL OF ORGANIC CHEMISTRY, 2022, 87 (15): : 10441 - 10448
  • [50] N-Heterocyclic carbene/palladium synergistic catalysis in organic synthesis
    Debnath, Chhanda
    Bhoi, Saswat Ranjan
    Gandhi, Shikha
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2024, 22 (23) : 4613 - 4624
12345