N-Heterocyclic Carbene Catalysis for Polycyclic Benzazepines Assembly: Regioselective Intramolecular Tandem Radical Cyclization

被引：2
|
作者：
Feng, Zhiming [1 ]
Wu, Lili [1 ]
Zhou, Cong-Ying [1 ]
Wang, Chengming [1 ]
机构：
[1] Jinan Univ, Coll Chem & Mat Sci, Guangzhou 511443, Guangdong, Peoples R China
来源：
ORGANIC LETTERS | 2024年 / 26卷 / 42期
关键词：
D O I：
10.1021/acs.orglett.4c03303
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A variety of polycyclic benzazepines were rapidly constructed by NHC-catalyzed regioselective redox-neutral intramolecular tandem cyclization. Initial mechanistic studies revealed that a SET radical process was possibly involved.
引用
收藏
页码：9068 / 9072
页数：5
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