Photocatalytic Deoxygenative Alkylation with Alcohols via Xanthates or Thionocarbonates

被引:0
|
作者
Luo, Wei [1 ]
Chen, Zhong [1 ,3 ]
Yu, Bing [2 ]
机构
[1] Xinyang Agr & Forestry Univ, Coll Pharm, Xinyang 464000, Peoples R China
[2] Zhengzhou Univ, Coll Chem, Zhengzhou 450001, Peoples R China
[3] Nanjing Forestry Univ, Natl Engn Res Ctr Low Carbon Proc & Utilizat Fores, Nanjing 210037, Peoples R China
基金
中国国家自然科学基金;
关键词
alkylation; photocatalytic synthesis; alcohols; visible-light-induced; alkyl radical; xanthates; thionocarbonates; C-O BONDS; BORROWING HYDROGEN; FRAGMENTATION; ACTIVATION; GENERATION; ARYLATION; CATALYST; ESTERS; AMIDES;
D O I
10.1002/ajoc.202400627
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Recent advancements in photocatalytic strategies have expanded the range of alkylating agents, including alkyl carboxylic acids and saturated hydrocarbons. Notably, alcohols are preferred for their availability, stability, and safety compared to traditional alkylating reagents such as alkyl halides. This review summarizes recent developments in photocatalytic deoxygenative alkylation using alcohols, specifically through the formation of xanthates or thionocarbonates.
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页数:8
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