Photocatalytic Deoxygenative Alkylation with Alcohols via Xanthates or Thionocarbonates

被引：0
|
作者：
Luo, Wei [1 ]
Chen, Zhong [1 ,3 ]
Yu, Bing [2 ]
机构：
[1] Xinyang Agr & Forestry Univ, Coll Pharm, Xinyang 464000, Peoples R China
[2] Zhengzhou Univ, Coll Chem, Zhengzhou 450001, Peoples R China
[3] Nanjing Forestry Univ, Natl Engn Res Ctr Low Carbon Proc & Utilizat Fores, Nanjing 210037, Peoples R China
来源：
ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2025年 / 14卷 / 03期
基金：
中国国家自然科学基金;
关键词：
alkylation; photocatalytic synthesis; alcohols; visible-light-induced; alkyl radical; xanthates; thionocarbonates; C-O BONDS; BORROWING HYDROGEN; FRAGMENTATION; ACTIVATION; GENERATION; ARYLATION; CATALYST; ESTERS; AMIDES;
D O I：
10.1002/ajoc.202400627
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Recent advancements in photocatalytic strategies have expanded the range of alkylating agents, including alkyl carboxylic acids and saturated hydrocarbons. Notably, alcohols are preferred for their availability, stability, and safety compared to traditional alkylating reagents such as alkyl halides. This review summarizes recent developments in photocatalytic deoxygenative alkylation using alcohols, specifically through the formation of xanthates or thionocarbonates.
引用
收藏
页数：8
相关论文
共 50 条
  • [21] Benzothiazolium salts as reagents for the deoxygenative perfluoroalkylthiolation of alcohols
    Ariamajd, Armin
    Gerwien, Nils J.
    Schwabe, Benjamin
    Dix, Stefan
    Hopkinson, Matthew N.
    BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 2021, 17 : 83 - 88
  • [22] Deoxygenative gem-difluorovinylation of aliphatic alcohols
    Xia, Guang-Da
    He, Yuan-Yuan
    Zhang, Jing
    Liu, Zi-Kui
    Gao, Yang
    Hu, Xiao-Qiang
    CHEMICAL COMMUNICATIONS, 2022, 58 (47) : 6733 - 6736
  • [23] Metallaphotoredox-enabled deoxygenative arylation of alcohols
    Zhe Dong
    David W. C. MacMillan
    Nature, 2021, 598 : 451 - 456
  • [24] Deoxygenative α-alkylation and α-arylation of 1,2-dicarbonyls
    Jin, Shengfei
    Dang, Hang T.
    Haug, Graham C.
    Nguyen, Viet D.
    Arman, Hadi D.
    Larionov, Oleg, V
    CHEMICAL SCIENCE, 2020, 11 (34) : 9101 - 9108
  • [25] Multifunctional Catalysts for Direct Conversion of Alcohols to Long-Chain Hydrocarbons via Deoxygenative Olefination
    Ainembabazi, Diana
    Horlyck, Jonathan
    Dolan, Darren
    Finn, Matthew
    Lee, Adam Fraser
    Wilson, Karen
    Voutchkova-Kostal, Adelina
    ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2021, 9 (44) : 14657 - 14662
  • [26] Synthesis of sulfinamides via photocatalytic alkylation or arylation of sulfinylamine
    Yan, Ming
    Wang, Si-fan
    Zhang, Yong-po
    Zhao, Jin-zhong
    Tang, Zhuo
    Li, Guang-xun
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2024, 22 (02) : 348 - 352
  • [27] Photocatalytic Strategies for the Synthesis of Xanthates and Their Analogues
    Geniller, Lilian
    Taillefer, Marc
    Jaroschik, Florian
    Prieto, Alexis
    SYNTHESIS-STUTTGART, 2025,
  • [28] Electroactivated alkylation of amines with alcohols via borrowing hydrogen methodology
    Appiagyei, Benjamin
    Bhatia, Souful
    Keeney, Gabriela
    Jackson, James
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 257
  • [29] MILD AND EFFICIENT CONVERSION OF ALLYLIC ALCOHOLS TO XANTHATES
    SURYAWANSHI, SN
    RANI, A
    BHAKUNI, DS
    SYNTHETIC COMMUNICATIONS, 1990, 20 (05) : 625 - 632
  • [30] Electrochemically Driven Deoxygenative Borylation of Alcohols and Carbonyl Compounds
    Guan, Weiyang
    Chang, Yejin
    Lin, Song
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2023, 145 (31) : 16966 - 16972
12345