Construction of CuO-ZnO-Al2O3/CeO2 catalyst via the shape effect for methanol steam reforming

被引：0
|
作者：
Liao, Moyu [1 ,2 ]
Xiang, Ruofei [1 ,2 ]
Tan, Xinyu [1 ,2 ]
Dai, Zhongxu [1 ,2 ]
Qin, Hang [3 ]
Xiao, Hanning [3 ]
机构：
[1] College of Materials and Chemical Engineering, Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion Materials, China Three Gorges University, Yichang,443002, China
[2] Hubei Three Gorges Laboratory, Yichang,443007, China
[3] College of Materials Science and Engineering, Hunan University, Changsha,410082, China
来源：
Renewable Energy | 2025年 / 247卷
基金：
中国国家自然科学基金;
关键词：
Catalysts - Catalytic reforming - Cerium oxide - Gas adsorption - Hydrothermal synthesis - Nanoclay - Oxygen vacancies - Steam;
D O I：
10.1016/j.renene.2025.123054
中图分类号：
学科分类号：
摘要：
CuO-ZnO-Al2O3/CeO2 catalysts based on CeO2 nanocubes (CeO2-NC), nanopolyhedrons (CeO2-NP), and nanorods (CeO2-NR) were synthesized by hydrothermal and incipient impregnation methods, and their catalytic performance in methanol steam reforming was tested. The correlation between the activity data and the physicochemical properties of the catalysts indicated that the micromorphology of the CeO2 support significantly influenced the catalytic performance. The excellent reactivity of CuO-ZnO-Al2O3/CeO2-NR with 100 % methanol conversion rate at 280 °C was attributed to the small particles with large specific surface area, abundant oxygen vacancies and chemisorbed oxygen, superior reducibility and strong methanol adsorption capacity. Meanwhile, the strong interaction between CuO-ZnO-Al2O3 and CeO2-NR greatly improved the catalytic efficiency. Besides, CuO-ZnO-Al2O3/CeO2-NR showed the lowest CO selectivity of 0.41–1.86 % in the range of 230–280 °C and a stability of over 40 h at 280 °C, demonstrating its potential as an excellent catalyst for methanol steam reforming. © 2025
引用
收藏
相关论文
共 50 条
  • [21] Study of the effect of preparation method on CuO-ZnO-Al2O3 catalyst
    Ning, WS
    Shen, HY
    Liu, HH
    APPLIED CATALYSIS A-GENERAL, 2001, 211 (02) : 153 - 157
  • [22] Dependence of the CeO2 morphology in CuO/CeO2 catalysts for the oxidative steam reforming of methanol
    Eaimsumang, Srisin
    Petchakan, Sivinee
    Luengnaruemitchai, Apanee
    REACTION KINETICS MECHANISMS AND CATALYSIS, 2019, 127 (02) : 669 - 690
  • [23] Dependence of the CeO2 morphology in CuO/CeO2 catalysts for the oxidative steam reforming of methanol
    Srisin Eaimsumang
    Sivinee Petchakan
    Apanee Luengnaruemitchai
    Reaction Kinetics, Mechanisms and Catalysis, 2019, 127 : 669 - 690
  • [24] In Situ Reduction of a CuO/ZnO/CeO2/ZrO2 Catalyst Washcoat Supported on Al2O3 Foam Ceramic by Glycerol for Methanol Steam Reforming in a Microreactor
    Liao, Moyu
    Qin, Hang
    Guo, Wenming
    Gao, Pengzhao
    Xiao, Hanning
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2021, 60 (25) : 8991 - 9001
  • [25] Oxidative methanol steam reforming on a highly dispersed CuO/CeO2/Al2O3 catalyst prepared by a single-step method
    Turco, Maria
    Cammarano, Claudia
    Bagnasco, Giovanni
    Moretti, Elisa
    Storaro, Loretta
    Talon, Aldo
    Lenarda, Maurizio
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2009, 91 (1-2) : 101 - 107
  • [26] CO formation/selectivity for steam reforming of methanol with a commercial CuO/ZnO/Al2O3 catalyst
    Purnama, H
    Ressler, T
    Jentoft, RE
    Soerijanto, H
    Schlögl, R
    Schomäcker, R
    APPLIED CATALYSIS A-GENERAL, 2004, 259 (01) : 83 - 94
  • [27] Steam Reforming of Dimethoxymethane, Methanol and Dimethyl Ether on CuO-ZnO/γ-Al2O3 Catalyst
    Pechenkin, A. A.
    Badmaev, S. D.
    Belyaev, V. D.
    Paukshtis, E. A.
    Stonkus, O. A.
    Sobyanin, V. A.
    KINETICS AND CATALYSIS, 2017, 58 (05) : 577 - 584
  • [28] One-step growth of CuO/ZnO/CeO2/ZrO2 nanoflowers catalyst by hydrothermal method on Al2O3 support for methanol steam reforming in a microreactor
    Liao, Moyu
    Guo, Chenxu
    Guo, Wenming
    Hu, Tianci
    Xie, Jiawei
    Gao, Pengzhao
    Xiao, Hanning
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2021, 46 (14) : 9280 - 9291
  • [29] Durability of Ru/CeO2/γ-Al2O3 Catalyst for Steam Reforming of Dodecane
    Muramoto, Tomoya
    Nariai, Ken-taro
    Ohara, Hiroaki
    Kamata, Hiroyuki
    JOURNAL OF THE JAPAN PETROLEUM INSTITUTE, 2009, 52 (03) : 108 - 113
  • [30] Mechanistic aspects of the steam reforming of methanol over a CuO/ZnO/ZrO2/Al2O3 catalyst
    Breen, JP
    Meunier, FC
    Ross, JRH
    CHEMICAL COMMUNICATIONS, 1999, (22) : 2247 - 2248
12345