Absolute Helix-Sense-Selective Polymerization Using Circularly Polarized Light in One-Handed Helical Channels

被引：0

作者：

Huang, Shuaishuai ^{[1
]}

Teraguchi, Masahiro ^{[2
]}

Kaneko, Takashi ^{[2
]}

Aoki, Toshiki ^{[2
]}

机构：

[1] Niigata Univ, Grad Sch Sci & Technol, Ikarashi 2-8050,Nishi Ku, Niigata 9502181, Japan

[2] Niigata Univ, Grad Sch Sci & Technol, Dept Chem & Chem Engn, Ikarashi 2-8050,Nishi Ku, Niigata 9502181, Japan

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2025年

关键词：

absolute symmetric polymerization; circularly polarized light; helix-sense-selective polymerization; highly selective photocyclic aromatization; one-handed helical channels; ENANTIOSELECTIVE SYNTHESIS; ASYMMETRIC-SYNTHESIS;

D O I：

10.1002/marc.202500185

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Absolute helix-sense-selective polymerization of an achiral acetylene monomer (1) in one-handed helical channels created with helix-sense-selective decomposition of (+/-)-poly1 using circularly polarized light is realized with no chiral compounds. In addition, the relative optical yield (%ee) of the formed oligomers is controlled by those of the one-handed helical channels.

引用

页数：4

共 35 条

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