Absolute Helix-Sense-Selective Polymerization Using Circularly Polarized Light in One-Handed Helical Channels

被引：0
|
作者：
Huang, Shuaishuai [1 ]
Teraguchi, Masahiro [2 ]
Kaneko, Takashi [2 ]
Aoki, Toshiki [2 ]
机构：
[1] Niigata Univ, Grad Sch Sci & Technol, Ikarashi 2-8050,Nishi Ku, Niigata 9502181, Japan
[2] Niigata Univ, Grad Sch Sci & Technol, Dept Chem & Chem Engn, Ikarashi 2-8050,Nishi Ku, Niigata 9502181, Japan
来源：
MACROMOLECULAR RAPID COMMUNICATIONS | 2025年
关键词：
absolute symmetric polymerization; circularly polarized light; helix-sense-selective polymerization; highly selective photocyclic aromatization; one-handed helical channels; ENANTIOSELECTIVE SYNTHESIS; ASYMMETRIC-SYNTHESIS;
D O I：
10.1002/marc.202500185
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Absolute helix-sense-selective polymerization of an achiral acetylene monomer (1) in one-handed helical channels created with helix-sense-selective decomposition of (+/-)-poly1 using circularly polarized light is realized with no chiral compounds. In addition, the relative optical yield (%ee) of the formed oligomers is controlled by those of the one-handed helical channels.
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页数：4
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