A convenient synthesis of Os3(CO)12 from OsO4 and formic acid

被引：0

作者：

Kumaran, Elumalai ^{[1
]}

Leong, Weng Kee ^{[1
]}

机构：

[1] Nanyang Technol Univ, Sch Chem Chem Engn & Biotechnol, 62 Nanyang Dr, Singapore 637459, Singapore

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2025年 / 1025卷

关键词：

Osmium; Carbonyl cluster; Carbon monoxide; Formic acid; Synthesis; HYDROGENATION; OS3(CO)12; CLUSTERS;

D O I：

10.1016/j.jorganchem.2024.123480

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A convenient synthesis of the osmium carbonyl cluster Os3(CO)12 starting from osmium tetroxide and the in-situ generation of gaseous carbon monoxide via the decomposition of formic acid, is reported.

引用

页数：2

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