A convenient synthesis of Os3(CO)12 from OsO4 and formic acid

被引：0

作者：

Kumaran, Elumalai ^{[1
]}

Leong, Weng Kee ^{[1
]}

机构：

[1] Nanyang Technol Univ, Sch Chem Chem Engn & Biotechnol, 62 Nanyang Dr, Singapore 637459, Singapore

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2025年 / 1025卷

关键词：

Osmium; Carbonyl cluster; Carbon monoxide; Formic acid; Synthesis; HYDROGENATION; OS3(CO)12; CLUSTERS;

D O I：

10.1016/j.jorganchem.2024.123480

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A convenient synthesis of the osmium carbonyl cluster Os3(CO)12 starting from osmium tetroxide and the in-situ generation of gaseous carbon monoxide via the decomposition of formic acid, is reported.

引用

页数：2

共 50 条

[21] Synthesis of new thiol derivatives of [Os3(CO)12]; crystal structure of [Os3(CO)10(ae-H) (ae-SC(CH3)3)]
Inorg Chim Acta, 1 (131):
[22] Control of the photochemistry of Ru3(CO)12 and Os3(CO)12 by variation of the solvent
Leadbeater, NE
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 573 (1-2) : 211 - 216
[23] A STABILIZED CO2/OSO4 LASER WITH THE FREQUENCY REPRODUCIBILITY OF 10-12
BAZAROV, EN
GERASIMOV, GA
GUBIN, VP
SAZONOV, AI
STAROSTIN, NI
STRELNIKOV, VN
FOMIN, VV
KVANTOVAYA ELEKTRONIKA, 1987, 14 (11): : 2231 - 2237
[24] STUDIES OF THE PHOTOREACTIONS OF OS3(CO)12 WITH CHLOROCARBONS AND WITH TRIPHENYLPHOSPHINE IN SOLUTION
TYLER, DR
ALTOBELLI, M
GRAY, HB
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (09) : 3022 - 3024
[25] CO HYDROGENATION CATALYZED BY MAGNESIA-SUPPORTED OSMIUM DERIVED FROM OS3(CO)12
DEEBA, M
SCOTT, JP
BARTH, R
GATES, BC
JOURNAL OF CATALYSIS, 1981, 71 (02) : 373 - 380
[26] INTERACTION OF OS3(CO)12 WITH SILICA AND LANTHANUM OXIDE SUPPORTS
CHAKRABARTY, DK
DESAI, AA
INORGANICA CHIMICA ACTA, 1986, 118 (02) : 169 - 171
[27] SURFACE-MEDIATED ORGANOMETALLIC SYNTHESIS - FORMATION OF [OS5C(CO)14]2- FROM [OS3(CO)12] ON MGO
FUNG, AS
TOOLEY, PA
KELLEY, MJ
GATES, BC
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (05) : 371 - 372
[28] SPECTROSCOPIC STUDIES ON SILICA-SUPPORTED OS3(CO)12
DOSSI, C
PSARO, R
ZANONI, R
STONE, FS
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1987, 43 (12): : 1507 - 1510
[29] DEHYDROGENATION OF ORGANIC AND INORGANIC MOLECULES BY REACTION WITH OS3(CO)12
DEEMING, AJ
UNDERHILL, M
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1972, 42 (01) : C60 - +
[30] Al2O3-SUPPORTED Os3(CO)12 CATALYSTS FOR THE SYNTHESIS OF HYDROCARBONS FROM CO AND H2.
Lapidus, A.L.
Savel'ev, M.M.
Muranova, L.M.
Kondrat'ev, L.T.
Sominskii, S.D.
Kinetics and Catalysis, 1985, 26 (1 pt 2) : 216 - 219

← 1 2 3 4 5 →