A convenient synthesis of Os3(CO)12 from OsO4 and formic acid

被引：0
|
作者：
Kumaran, Elumalai [1 ]
Leong, Weng Kee [1 ]
机构：
[1] Nanyang Technol Univ, Sch Chem Chem Engn & Biotechnol, 62 Nanyang Dr, Singapore 637459, Singapore
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2025年 / 1025卷
关键词：
Osmium; Carbonyl cluster; Carbon monoxide; Formic acid; Synthesis; HYDROGENATION; OS3(CO)12; CLUSTERS;
D O I：
10.1016/j.jorganchem.2024.123480
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A convenient synthesis of the osmium carbonyl cluster Os3(CO)12 starting from osmium tetroxide and the in-situ generation of gaseous carbon monoxide via the decomposition of formic acid, is reported.
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页数：2
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