Unlocking an additive-free and catalyst-free dual approach for reduction of amides to amines

被引：0

作者：

Chowdhury, Deep ^{[1
]}

Mukherjee, Arup ^{[1
]}

机构：

[1] Indian Inst Technol Bhilai, Dept Chem, Durg 491002, Chhattisgarh, India

来源：

CHEMICAL COMMUNICATIONS | 2025年 / 61卷 / 08期

关键词：

HYDROGENATION;

D O I：

10.1039/d4cc04606d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report a two-fold strategy to convert amides to amines in the presence of dimethylamine-borane as the hydrogen source. In the absence of any additive, the formation of the amines resulted from reduction of the amides. On the other hand, in the presence of TMEDA and dimethylamine-borane, tertiary amines were obtained from primary amides in a one-pot fashion.

引用

页码：1605 / 1608

页数：4

共 50 条

[41] Strategies Toward the Catalyst-Free α-C–H Functionalizations of Tertiary Amines
Mohit L. Deb
Pranjal K. Baruah
Topics in Current Chemistry, 2023, 381
[42] A facile, catalyst- and additive-free, and scalable approach to the photochemical preparation of disulfides from organosulfenyl chlorides
Liu, Wei
Wang, Jiayi
Song, Gonghua
RSC ADVANCES, 2024, 14 (44) : 32200 - 32205
[43] A highly efficient catalyst-free cycloisomerization approach to indolizinones
Kim, Ikyon
Choi, Jihyun
Lee, Sunkyung
Lee, Ge Hyeong
SYNLETT, 2008, (15) : 2334 - 2338
[44] The Synthesis of Amides from Benzoic Acids and Dicarbodiimides Under Catalyst-Free Conditions
Wu, Fengtian
Yan, Fangming
Zeng, Rong
Sun, Yijia
Liu, Xiuping
Zhang, Caihong
Chen, Yenan
Wu, Ling
Cui, Chunna
LETTERS IN ORGANIC CHEMISTRY, 2023, 20 (03) : 221 - 229
[45] Visible-light-assisted and catalyst-free intramolecular hydroamidation of allenyl amides
Liu, Lu
Ward, Robert
Schomaker, Jennifer
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 257
[46] Easy Access to Tertiary Amines from Carbonyl Compounds with Substituted Amine-Boranes: A Substrate, Catalyst, and Additive-Free Approach Under Mild Conditions
Chowdhury, Deep
Mukherjee, Arup
CHEMISTRY-AN ASIAN JOURNAL, 2023, 18 (20)
[47] Catalyst- and Additive-Free Direct Synthesis of N-Sulfonyl Guanidines
Maierhaba, Julaiti
Bulunuer, Yusan
Abudureheman, Wusiman
CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2024, 44 (04) : 1276 - 1283
[48] Catalyst-free synthesis of silicon nanowires by oxidation and reduction process
Behura, Sanjay K.
Yang, Qiaoqin
Hirose, Akira
Jani, Omkar
Mukhopadhyay, Indrajit
JOURNAL OF MATERIALS SCIENCE, 2014, 49 (10) : 3592 - 3597
[49] Additive-Free Decarboxylative Coupling of Cinnamic Acid Derivatives in Water: Synthesis of Allyl Amines
Park, Kyungho
Lee, Sunwoo
ORGANIC LETTERS, 2015, 17 (05) : 1300 - 1303
[50] Additive-free ferroelectric thick films
Pearce, DH
Button, TW
GROWTH AND PROCESSING OF ELECTRONIC MATERIALS, 1998, : 87 - 93

← 1 2 3 4 5 →