The Second Law of Thermodynamics and the Surface Characteristics of Dispersed Systems

被引：0

作者：

Tovbin, Yu. K. ^{[1
]}

机构：

[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119071, Russia

来源：

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2024年 / 98卷 / 12期

关键词：

small systems; thermodynamics; phase; dispersed systems; surface tension;

D O I：

10.1134/S0036024424702078

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An analysis of the literature shows that all surface characteristics of dispersed systems (surface tensions, contact angles, disjoining pressure, and the properties of small systems) have ambiguous thermodynamic definitions. The second law of Clausius thermodynamics, which requires additional experimental data on the periods of relaxation of momentum, energy, and mass transfer processes, is used to eliminate this ambiguity.

引用

页码：2823 / 2827

页数：5

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