Synthesis of the 3,5,3',5'-3H4-2,2'-diphenyleneiodonium cation and of its 4-nitro derivative

被引：0

作者：

Berthon, Jean-Luc ^{[1
]}

Dias, Marylène ^{[1
]}

Mornet, René ^{[1
]}

Camadro, Jean-Michel ^{[2
]}

机构：

[1] Lab. Ingenierie Molec. Mat. Organ., Faculté des Sciences, 2 Boulevard Lavoisier, 49045 Angers Cedex, France

[2] Lab. d'Ingenierie Proteines C., Institut Jacques Monod, 2 Place Jussieu, 75251 Paris Cedex 05, France

来源：

Journal of Labelled Compounds and Radiopharmaceuticals | 2000年 / 43卷 / 05期

关键词：

D O I：

10.1002/(SICI)1099-1344(200004)43:53.0.CO;2-V

中图分类号：

学科分类号：

摘要：

The 3,5,3',5'-3H4-2,2'-diphenyleneiodonium cation [3H]-1 was synthesized in three steps from cold 2,2'-diaminodiphenyl. The nitration of [3H]-1 gave easily the 4-nitro derivative [3H]-2. These two compounds which contain four tritium labels were obtained with a high specific activity, and are proposed as tools to study the interaction of 2,2'-diphenyleneiodonium cations with redox enzymes, especially flavoproteins.

引用

页码：515 / 522

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