Synthesis of the 3,5,3',5'-3H4-2,2'-diphenyleneiodonium cation and of its 4-nitro derivative

被引：0
|
作者：
Berthon, Jean-Luc [1 ]
Dias, Marylène [1 ]
Mornet, René [1 ]
Camadro, Jean-Michel [2 ]
机构：
[1] Lab. Ingenierie Molec. Mat. Organ., Faculté des Sciences, 2 Boulevard Lavoisier, 49045 Angers Cedex, France
[2] Lab. d'Ingenierie Proteines C., Institut Jacques Monod, 2 Place Jussieu, 75251 Paris Cedex 05, France
来源：
Journal of Labelled Compounds and Radiopharmaceuticals | 2000年 / 43卷 / 05期
关键词：
D O I：
10.1002/(SICI)1099-1344(200004)43:53.0.CO;2-V
中图分类号：
学科分类号：
摘要：
The 3,5,3',5'-3H4-2,2'-diphenyleneiodonium cation [3H]-1 was synthesized in three steps from cold 2,2'-diaminodiphenyl. The nitration of [3H]-1 gave easily the 4-nitro derivative [3H]-2. These two compounds which contain four tritium labels were obtained with a high specific activity, and are proposed as tools to study the interaction of 2,2'-diphenyleneiodonium cations with redox enzymes, especially flavoproteins.
引用
收藏
页码：515 / 522
相关论文
共 50 条
  • [41] Synthesis of new 1,1′-di(4-nitro or 2-nitrophenyl)-5,5′-disubstituted 3,3′-bipyrazoles under microwave irradiation and classical heating conditions
    Bouabdallah, Ibrahim
    Touzani, Rachid
    Zidane, Ismail
    Ramdani, Abdelkrim
    Radi, Smaail
    ARKIVOC, 2006, : 46 - 52
  • [42] Inhibition of 3,3',4,4',5-pentachlorobiphenyl-induced chicken embryotoxicity by 2,2',4,4',5,5'-hexachlorobiphenyl
    Zhao, F
    Mayura, K
    Kocurek, N
    Edwards, JF
    Kubena, LF
    Safe, SH
    Phillips, TD
    FUNDAMENTAL AND APPLIED TOXICOLOGY, 1997, 35 (01): : 1 - 8
  • [43] Synthesis and Antifungal Activity of 2-Substituted Sulfinyl (Sulfonyl)-5-(4-nitro or 4-methoxyphenyl)-1,3,4-thiadiazole Derivatives
    Yang, Chao
    Yang, Song
    Song, Baoan
    Hu, Deyu
    Chen, Hongjun
    Xue, Wei
    Jin, Linhong
    Wu, Jian
    Xu, Weiming
    Bai, Song
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2010, 30 (09) : 1327 - 1334
  • [44] SYNTHESIS OF 2,2'-DISUBSTITUTED + 2,2',3,3'-TETRASUBSTITUTED [6,6'-BIQUINAZOLINE]-4,4'(3H,3'H)-DIONES
    SUTHAR, BP
    INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 1982, 21 (06): : 588 - 589
  • [45] 1,1′,3,3′,5,5′-Hexamethylspiro[furo[2,3-d]pyrimidine-6(5H),5′-pyrimidine]-2,2′,4,4′,6′(1H,3H,1′H,3′H,5′H)-pentaone
    Pesyan, Nader Noroozi
    Rastgar, Saeed
    Hosseini, Yaser
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O1444 - U3327
  • [46] NITRO ENOL, 3-HYDROXY-4-NITRO-5-PHENYL-3-PYRROLIN-2-ONE, AND ITS REACTIVE METHYL ETHER
    SOUTHWICH, PL
    FITZGERA.JA
    MADHAV, R
    WELSH, DA
    JOURNAL OF ORGANIC CHEMISTRY, 1969, 34 (11): : 3279 - +
  • [47] 1,2,5-THIADIAZOLE DERIVATIVES .4. SYNTHESIS AND SUBSTITUTION-REACTIONS OF 4-AZA-6-BROMO-2,I,3-BENZOTHIADIAZOLE AND 5-BROMO-2-1,3-BENZOTHIADIAZOLE AND ITS 4-NITRO DERIVATIVE
    SHARMA, KS
    SINGH, RP
    SINGH, V
    INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 1979, 17 (01): : 13 - 16
  • [48] SYNTHESIS OF 3,5,3],5]-HALOGEN-SUBSTITUTED THYROPROPIONIC ACIDS
    MATSUURA, T
    JOURNAL OF MEDICINAL CHEMISTRY, 1964, 7 (06) : 830 - &
  • [49] THE VIBRATIONAL-SPECTRA AND MOLECULAR-STRUCTURE OF 3,3'-DIBROMOBIPHENYL, 3,5,4'-TRIBROMOBIPHENYL AND 3,5,3',5'-TETRABROMOBIPHENYL
    HORN, A
    KLAEBOE, P
    KLOSTERJENSEN, E
    CYVIN, BN
    CYVIN, SJ
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1985, 41 (03): : 451 - 463
  • [50] HEPATIC MICROSOMAL-ENZYME INDUCTION BY 2,2',3,3',4,4'-HEXACHLOROBIPHENYL AND 2,2',3',4,4',5-HEXACHLOROBIPHENYL
    PARKINSON, A
    ROBERTSON, LW
    SAFE, S
    LIFE SCIENCES, 1980, 27 (24) : 2333 - 2337
12345