Synthesis of Glycidol from Allyl Alcohol and Alkyl Aromatic Hydroperoxides.

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作者
Farberov, M.I.
Bobylev, B.N.
Liakumovich, A.G.
Rutman, G.I.
Mel'nik, L.V.
Subbotina, I.V.
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HYDROCARBONS; -; Derivatives;
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A method of synthesizing glycidol by the epoxidation of allyl alcohol with isopropylbenzene hydroperoxide is proposed. It is shown that by this method it is possible to obtain glycidol with a high yield (90-96 mol% per unreacted reagents) and a very high degree of purity. A special feature of this process is that the epoxidation is carried out in a paraffin hydrocarbon medium, thus considerably simplifying the separation of the reaction products.
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页码:14 / 17
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