Radiotracer examination of gas-liquid separators used in arsenic speciation by hydride generation - AAS

被引:0
|
作者
Van Elteren, J.T. [1 ]
Das, H.A. [1 ]
Bax, D. [1 ]
机构
[1] Netherlands Energy Res. Foundation, P.O. Box 1, 1755 ZG Petten, Netherlands
关键词
Gases; -; Hydrides; Radioactivity;
D O I
暂无
中图分类号
学科分类号
摘要
Two types of gas-liquid separators for use in on-line hydride generation AAS have been examined: the 'classical' one, in which gas and liquid are separated by gravity and that based on diffusion through a permeable tube. Results are presented for the determination of arsenic species (arsenite, As(III); arsenate, As(V); monomethylarsonic acid, MMAA; dimethylarsenic acid, DMAA). Yield (of hydride generation and gas-liquid separation) and response time are investigated as functions of the experimental variables. It is concluded that in conjunction with a cold trap, only the 'classical' gas-liquid separator is satisfactory.
引用
收藏
页码:133 / 144
相关论文
共 50 条
  • [41] Flow injection electrochemical hydride generation atomic absorption spectrometry (FI-EHG-AAS) as a simple device for the speciation of inorganic arsenic and selenium
    U. Pyell
    A. Dworschak
    F. Nitschke
    B. Neidhart
    Fresenius' Journal of Analytical Chemistry, 1999, 363 : 495 - 498
  • [42] Speciation of organic arsenic species by using liquid chromatography coupled with hydride-generation atomic absorption spectrometry
    Jin, OY
    Yan, S
    Zhang, XR
    CHINESE JOURNAL OF ANALYTICAL CHEMISTRY, 1999, 27 (10) : 1151 - 1155
  • [43] Speciation of arsenic(III) and arsenic(V) in sediment extracts by high-performance liquid chromatography hydride generation atomic absorption spectrophotometry
    Manning, BA
    Martens, DA
    ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1997, 31 (01) : 171 - 177
  • [44] Speciation of toxicologically important arsenic species in human serum by liquid chromatography hydride generation atomic absorption spectrometry
    Zhang, XR
    Cornelis, R
    deKimpe, J
    Mees, L
    JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 1996, 11 (11) : 1075 - 1079
  • [45] On line coupling HPLC and quartz surface-induced luminescence FPD with hydride generation and microporous membrane gas-liquid separator as interface for the speciation of methyltins
    Zhai, Guangshu
    Liu, Jingfu
    Jiang, Guibin
    He, Bin
    Zhou, Qunfang
    JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 2007, 22 (11) : 1420 - 1426
  • [46] ARSENIC SPECIATION BY CAPILLARY GAS-LIQUID-CHROMATOGRAPHY
    DIX, K
    CAPPON, CJ
    TORIBARA, TY
    JOURNAL OF CHROMATOGRAPHIC SCIENCE, 1987, 25 (04) : 164 - 169
  • [47] EXAMINATION OF GAS-LIQUID FLOW IN A VENTURI SCRUBBER
    VISWANATHAN, S
    GNYP, AW
    STPIERRE, CC
    INDUSTRIAL & ENGINEERING CHEMISTRY FUNDAMENTALS, 1984, 23 (03): : 303 - 308
  • [48] A GAS-LIQUID CHROMATOGRAPHIC EXAMINATION OF STILBENE DERIVATIVES
    HEMINGWAY, RW
    HILLIS, WE
    BRUERTON, K
    JOURNAL OF CHROMATOGRAPHY, 1970, 50 (03): : 391 - +
  • [49] EXAMINATION OF HAMMETT EQUATION FOR GAS-LIQUID CHROMATOGRAPHY
    KARGER, BL
    ELMEHRIK, Y
    STERN, RL
    ANALYTICAL CHEMISTRY, 1968, 40 (08) : 1227 - &
  • [50] A Critical Investigation of Hydride Generation-Based Arsenic Speciation in Sulfidic Waters
    Planer-Friedrich, Britta
    Wallschlaeger, Dirk
    ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2009, 43 (13) : 5007 - 5013