Radiotracer examination of gas-liquid separators used in arsenic speciation by hydride generation - AAS

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作者
Van Elteren, J.T. [1 ]
Das, H.A. [1 ]
Bax, D. [1 ]
机构
[1] Netherlands Energy Res. Foundation, P.O. Box 1, 1755 ZG Petten, Netherlands
关键词
Gases; -; Hydrides; Radioactivity;
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摘要
Two types of gas-liquid separators for use in on-line hydride generation AAS have been examined: the 'classical' one, in which gas and liquid are separated by gravity and that based on diffusion through a permeable tube. Results are presented for the determination of arsenic species (arsenite, As(III); arsenate, As(V); monomethylarsonic acid, MMAA; dimethylarsenic acid, DMAA). Yield (of hydride generation and gas-liquid separation) and response time are investigated as functions of the experimental variables. It is concluded that in conjunction with a cold trap, only the 'classical' gas-liquid separator is satisfactory.
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页码:133 / 144
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