Monoclinic form of [Cu(C10H24N4)]CuCl4

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作者：
Washington State Univ, Pullman, United States [1 ]
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Acta Crystallogr Sect C Cryst Struct Commun | / pt 3卷 / 581-583期
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Acetone - Copper - Crystal atomic structure - Crystal growth - Diffusion - Ions - Organometallics - Solutions;
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摘要：
The monoclinic form of 1,4,8,11-tetraazacyclotetradecanecopper(II) tetrachlorocuprate, [Cu(14-ane)]CuCl4, has a chain structure consisting of Cu(14-ane)2+ cations linked by CuCl42- anions. The CuII ion has square-planar coordination in the cation [average Cu - N distance = 2.020 (7) angstrom] while the anion has flattened tetrahedral coordination geometry [average Cu - Cl distance = 2.246 (13) angstrom with average trans Cl - Cu - Cl angles = 130 (1)°]. The cations and anions are linked by semi-coordinate Cu&middot&middot&middotCl bonds with a distance of 2.855 (2) angstrom to form chains which run parallel to the c axis and pack in a hexagonal array.
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