Monoclinic form of [Cu(C10H24N4)]CuCl4

被引：0
|
作者：
Washington State Univ, Pullman, United States [1 ]
机构：
来源：
Acta Crystallogr Sect C Cryst Struct Commun | / pt 3卷 / 581-583期
关键词：
Acetone - Copper - Crystal atomic structure - Crystal growth - Diffusion - Ions - Organometallics - Solutions;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The monoclinic form of 1,4,8,11-tetraazacyclotetradecanecopper(II) tetrachlorocuprate, [Cu(14-ane)]CuCl4, has a chain structure consisting of Cu(14-ane)2+ cations linked by CuCl42- anions. The CuII ion has square-planar coordination in the cation [average Cu - N distance = 2.020 (7) angstrom] while the anion has flattened tetrahedral coordination geometry [average Cu - Cl distance = 2.246 (13) angstrom with average trans Cl - Cu - Cl angles = 130 (1)°]. The cations and anions are linked by semi-coordinate Cu&middot&middot&middotCl bonds with a distance of 2.855 (2) angstrom to form chains which run parallel to the c axis and pack in a hexagonal array.
引用
收藏
相关论文
共 50 条
  • [31] STRUCTURES OF BIS(4-AMINOPYRIDINIUM) TETRACHLOROCUPRATE(II) MONOHYDRATE, [C5H7N2]2[CUCL4].H2O, AND BIS(2-AMINO-3-HYDROXYPYRIDINIUM) TETRACHLOROCUPRATE(II), [C5H7N2O]2[CUCL4] - CORRELATION OF CUCL42- GEOMETRY WITH HYDROGEN-BONDING AND ELECTRONIC-STRUCTURE
    HALVORSON, KE
    PATTERSON, C
    WILLETT, RD
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1990, 46 : 508 - 519
  • [32] Preparation and Characterization of Hybrid Perovskite (NH3C6H12NH3)CuCl4
    Yang Zhi-Sheng
    Ke Wei-Fang
    Wang Yan-Xiang
    Huang Li-Qun
    Guo Ping-Chun
    Zhu Hua
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2017, 33 (09) : 1568 - 1572
  • [33] CRYSTAL-STRUCTURE OF THE SUPRAMOLECULAR SILVER(I)THIOCYANATE CYCLAM COMPLEX [AG(SCN)CENTER-DOT(C10H24N4)(1/2)]
    PICKARDT, J
    SHEN, J
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1994, 49 (02): : 211 - 214
  • [34] CRITICAL BEHAVIOR OF PERPENDICULAR SUSCEPTIBILITY OF ANTIFERROMAGNETIC (C2H5NH3)2 CUCL4
    JONGH, LJD
    SOLID STATE COMMUNICATIONS, 1972, 10 (06) : 537 - &
  • [35] Synthesis and Crystal Structure of a New Diamine Complex CuCl4（H2tn）
    张改
    张荣兰
    赵建社
    高新
    王少康
    何水样
    Chinese Journal of Chemistry, 2004, (09) : 899 - 902
  • [36] Synthesis and crystal structure of a new diamine complex CuCl4(H2tn)
    Zhang, G
    Zhang, RL
    Zhao, JS
    Gao, X
    Wang, SK
    He, SY
    CHINESE JOURNAL OF CHEMISTRY, 2004, 22 (09) : 899 - 902
  • [37] THE CRYSTAL AND MOLECULAR-STRUCTURE OF CINCHONINIUM TETRACHLOROCUPRATE 1.5-HYDRATE, (C19H24N2O)2+[CUCL4]2-.1.5H2O
    OLEKSYN, BJ
    HODOROWICZ, SA
    ACTA CRYSTALLOGRAPHICA SECTION A, 1984, 40 : C80 - C80
  • [38] Thermal properties of [N(C2H5)4]2CuCl4
    Tylczynski, Z
    Biskupski, P
    JOURNAL OF THE KOREAN PHYSICAL SOCIETY, 1998, 32 : S235 - S237
  • [39] Synthesis and Properties of C8H24N4（ClO4）4 and C8H24N4（NO3）4∙2H2O
    Liu, Wei
    Gou, Xiao-Dong
    Guo, Xiao-Zhuang
    Yang, Cai
    Hanneng Cailiao/Chinese Journal of Energetic Materials, 2024, 32 (11): : 1138 - 1144
  • [40] Crystal structure of [{[Ni(C10H24N4)][Ni(CN)4]}•-2H2O]n, a one-dimensional coordination polymer formed from the [Ni(cyclam)]2+ cation and the [Ni(CN)4]2- anion
    Tsymbal, Liudmyla, V
    Andriichuk, Irina L.
    Shova, Sergiu
    Lampeka, Yaroslaw D.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2021, 77 : 1140 - +
12345