Monoclinic form of [Cu(C10H24N4)]CuCl4

被引：0

作者：

Washington State Univ, Pullman, United States ^{[1
]}

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来源：

Acta Crystallogr Sect C Cryst Struct Commun | / pt 3卷 / 581-583期

关键词：

Acetone - Copper - Crystal atomic structure - Crystal growth - Diffusion - Ions - Organometallics - Solutions;

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摘要：

The monoclinic form of 1,4,8,11-tetraazacyclotetradecanecopper(II) tetrachlorocuprate, [Cu(14-ane)]CuCl4, has a chain structure consisting of Cu(14-ane)2+ cations linked by CuCl42- anions. The CuII ion has square-planar coordination in the cation [average Cu - N distance = 2.020 (7) angstrom] while the anion has flattened tetrahedral coordination geometry [average Cu - Cl distance = 2.246 (13) angstrom with average trans Cl - Cu - Cl angles = 130 (1)°]. The cations and anions are linked by semi-coordinate Cu&middot&middot&middotCl bonds with a distance of 2.855 (2) angstrom to form chains which run parallel to the c axis and pack in a hexagonal array.

引用

共 50 条

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[2] TETRAETHYLAMMONIUM TETRACHLOROCUPRATE(II), [N(C2H5)4]2[CUCL4]
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