USE OF A NEW IONIC DIOL FOR THE SYNTHESIS OF POLYURETHANE IONOMERS.

被引:0
|
作者
Chui, T.Y.T. [1 ]
Coote, A.S. [1 ]
Butler, C. [1 ]
George, M.H. [1 ]
Barrie, J.A. [1 ]
机构
[1] Imperial Coll, London, Engl, Imperial Coll, London, Engl
来源
Polymer communications Guildford | 1988年 / 29卷 / 02期
关键词
BIOMATERIALS - MICROANALYSIS - NUCLEAR MAGNETIC RESONANCE - POLYURETHANES - Synthesis - SPECTROSCOPY; INFRARED;
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摘要
A new ionic diol, potassium-S-1,2-dihydroxypropyl thiosulfate, TDOL, was synthesized by the nucleophilic attack of thiosulfate ions on 3-chloro-propane-1,2-diol. TDOL was used subsequently in step-growth polymerization to give a polyurethane ionomer. Both TDOL and the polyurethane ionomer were characterized by microanalysis, i. r. and n. m. r. The solubility characteristics of an ionic and non-ionic polyurethane in various liquids were determined.
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页码:40 / 42
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